Crystal structures of 2:1 inclusion complexes of xylidine isomers with 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol:: the importance of weak intermolecular interactions in crystal stability

被引：4

作者：

Toyota, S ^{[1
]}

Sawa, H ^{[1
]}

Asakura, M ^{[1
]}

Hirano, S ^{[1
]}

Toda, F ^{[1
]}

机构：

[1] Okayama Univ Sci, Fac Sci, Dept Chem, Okayama 7000005, Japan

来源：

CRYSTENGCOMM | 2001年 / 07期

关键词：

D O I：

10.1039/b009083m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular structures of inclusion complexes of the title host with 2,5-, 2,6- and 3,4-xylidines were determined by X-ray analysis. In addition to the relatively strong hydrogen bonds, intermolecular C-H . . . pi, N-H . . . pi and pi . . . pi interactions were found in the structures. The importance of these weak interactions is discussed in relation to the stability of the inclusion complexes.

引用

页数：3

共 50 条

[11] ISOLATION OF 2-MERCAPTOTROPONE AS A 2-1 COMPLEX WITH 1,1,6,6-TETRAPHENYLHEXA-2,4-DIYNE-1,6-DIOL AND X-RAY CRYSTAL-STRUCTURE OF THE COMPLEX [J].

TODA, F ;

TANAKA, K ;

ASAO, T ;

IKEGAMI, Y ;

TANAKA, N ;

HAMADA, K ;

FUJIWARA, T .

CHEMISTRY LETTERS, 1988, (03) :509-512

[12] COMPLEXATION WITH DIOL HOST COMPOUNDS .8. STRUCTURES AND THERMAL-ANALYSIS OF 1,1,6,6-TETRAPHENYLHEXA-2,4-DIYNE-1,6-DIOL WITH SELECTED KETONES [J].

JOHNSON, L ;

NASSIMBENI, LR ;

TODA, F .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1992, 48 :827-832

[13] SEPARATION OF CYCLOHEXANOL AND CYCLOHEXANONE BY COMPLEXATION WITH 1,1-DI(P-HYDROXYPHENYL)CYCLOHEXANE AND 1,1,6,6-TETRAPHENYLHEXA-2,4-DIYNE-1,6-DIOL AND CRYSTALLOGRAPHIC STRUCTURAL STUDIES OF THE COMPLEXES WITH THE FORMER HOST COMPOUND [J].

GOLDBERG, I ;

STEIN, Z ;

KAI, A ;

TODA, F .

CHEMISTRY LETTERS, 1987, (08) :1617-1620

[14] Complexation with diol host compounds.: Part 35:: Inclusion compounds of 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol with CCl4, CHCl3, CH2Cl2 and CH3CN [J].

Caira, MR ;

Jacobs, A ;

Nassimbeni, LR ;

Toda, E .

SUPRAMOLECULAR CHEMISTRY, 2004, 16 (02) :107-112

[15] COMPLEXATION WITH DIOL HOST COMPOUNDS .6. STRUCTURE AND DYNAMICS OF ENCLATHRATION BY 1,1,6,6-TETRAPHENYL-HEXA-2,4-DIYNE-1,6-DIOL [J].

BOND, DR ;

JOHNSON, L ;

NASSIMBENI, LR ;

TODA, F .

JOURNAL OF SOLID STATE CHEMISTRY, 1991, 92 (01) :68-79

[16] SOLID-STATE REACTIVITY OF COMPLEX-COMPOUNDS - THE NORRISH TYPE-II REACTION IN CRYSTALLINE 1,1,6,6-TETRAPHENYLHEXA-2,4-DIYNE-1,6-DIOL AND IN SOLID PARA-ISOPROPYLCALIX[8]ARENE [J].

VICENS, J .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1990, 187 :115-122

[17] STEREOSPECIFIC PHOTODIMERIZATION OF COUMARINS IN CRYSTALLINE INCLUSION COMPLEXES - MOLECULAR AND CRYSTAL-STRUCTURE OF 1-2 COMPLEX OF (S,S)-(-)-1,6-BIS(ORTHO-CHLOROPHENYL)-1,6-DIPHENYLHEXA-2,4-DIYNE-1,6-DIOL AND COUMARIN [J].

MOORTHY, JN ;

VENKATESAN, K .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (24) :6957-6960

[18] CRYSTAL-STRUCTURE OF A 1-1 INCLUSION COMPLEX OF (R,R)-(-)-1,6-BIS(O-CHLOROPHENYL)-1,6-DIPHENYLHEXA-2,4-DIYNE-1,6-DIOL AND (-)-(Z)-BENZYLIDENE-2-(3-METHYLBUTYL)AZANE OXIDE [J].

TODA, F ;

TANAKA, K ;

MAK, TCW .

CHEMISTRY LETTERS, 1989, (08) :1329-1330

[19] ENANTIOSELECTIVE PHOTOCYCLIZATION OF NITRONES INTO OXAZIRIDINES IN A CRYSTALLINE INCLUSION COMPLEX WITH OPTICALLY-ACTIVE 1,6-DI(ORTHO-CHLOROPHENYL)-1,6-DIPHENYLHEXA-2,4-DIYNE-1,6-DIOL [J].

TODA, F ;

TANAKA, K .

CHEMISTRY LETTERS, 1987, (11) :2283-2284

[20] ENANTIOSELECTIVE PHOTOREACTIONS OF TROPOLONE ALKYL ETHERS IN A CRYSTALLINE INCLUSION COMPLEX WITH OPTICALLY-ACTIVE 1,6-DI(ORTHO-CHLOROPHENYL)-1,6-DIPHENYLHEXA-2,4-DIYNE-1,6-DIOL [J].

TODA, F ;

TANAKA, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (18) :1429-1430

← 1 2 3 4 5 →