Solvophobicity and amphiphilic self-assembly in neoteric and nanostructured solvents

被引：21

作者：

Warr, Gregory G. ^{[1
,2
]}

Atkin, Rob ^{[3
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[2] Univ Sydney, Nano Inst, Sydney, NSW 2006, Australia

[3] Univ Western Australia, Sch Mol Sci, Perth, WA 6009, Australia

来源：

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE | 2020年 / 45卷

基金：

澳大利亚研究理事会;

关键词：

Ionic liquids; Amphiphilic; Nanostructure; Scattering; PROTIC IONIC LIQUID; DEEP EUTECTIC SOLVENTS; SPONTANEOUS VESICLE FORMATION; ANGLE NEUTRON-SCATTERING; SODIUM DODECYL-SULFATE; X-RAY-DIFFRACTION; MICELLE FORMATION; ETHYLAMMONIUM NITRATE; NONIONIC SURFACTANTS; PHASE-BEHAVIOR;

D O I：

10.1016/j.cocis.2019.12.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The emergence of ionic liquids and deep eutectics as neoteric solvents that support surfactant self-assembly creates a vast new playing field for creating new forms of soft matter with distinctive properties. Solvophobic self-assembly in ionic liquids and deep eutectics has unique and novel features arising from strong interactions between constituents, high ionic strengths, and the molecular structures of the components, which can induce amphiphilic nanostructure in these nonaqueous solvents. This nanostructure is often reminiscent of microemulsions and sponge phases. Here we review recent new understanding of solvent nanostructure and its effect on self-assembly of surfactants and lipids.

引用

页码：83 / 96

页数：14

共 138 条

[91] Structural Transitions of CTAB Micelles in a Protic Ionic Liquid [J].

Lopez-Barron, Carlos R. ;

Wagner, Norman J. .

LANGMUIR, 2012, 28 (35) :12722-12730

[92] Sponge-to-Lamellar Transition in a Double-Tail Cationic Surfactant/Protic Ionic Liquid System: Structural and Rheological Analysis [J].

Lopez-Barron, Carlos R. ;

Basavaraj, Madivala G. ;

DeRita, Leo ;

Wagner, Norman J. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2012, 116 (02) :813-822

[93] Effect of counterion competition on micellar growth horizons for cetyltrimethylammonium micellar surfaces: Electrostatics and specific binding [J].

Magid, LJ ;

Han, Z ;

Warr, GG ;

Cassidy, MA ;

Butler, PD ;

Hamilton, WA .

JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (40) :7919-7927

[94] Criteria for solvate ionic liquids [J].

Mandai, Toshihiko ;

Yoshida, Kazuki ;

Ueno, Kazuhide ;

Dokko, Kaoru ;

Watanabe, Masayoshi .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (19) :8761-8772

[95] Inhomogeneity in Ethylammonium Nitrate Acetonitrile Binary Mixtures: The Highest "Low q Excess" Reported to Date [J].

Mariani, Alessandro ;

Caminiti, Ruggero ;

Ramondo, Fabio ;

Salvitti, Giovanna ;

Mocci, Francesca ;

Gontrani, Lorenzo .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (15) :3512-3522

[96] Tunable Hydrophobic Eutectic Solvents Based on Terpenes and Monocarboxylic Acids [J].

Martins, Monia A. R. ;

Crespo, Emanuel A. ;

Pontes, Paula V. A. ;

Silva, Liliana P. ;

Buelow, Mark ;

Maximo, Guilherme J. ;

Batista, Eduardo A. C. ;

Held, Christoph ;

Pinho, Simao P. ;

Coutinho, Joao A. P. .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (07) :8836-8846

[97] Amphiphilically Nanostructured Deep Eutectic Solvents [J].

McDonald, Samila ;

Murphy, Thomas ;

Imberti, Silvia ;

Warr, Gregory G. ;

Atkin, Rob .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2018, 9 (14) :3922-3927

[98] Impact of water on the melting temperature of urea plus choline chloride deep eutectic solvent [J].

Meng, Xiangqian ;

Ballerat-Busserolles, Karine ;

Husson, Pascale ;

Andanson, Jean-Michel .

NEW JOURNAL OF CHEMISTRY, 2016, 40 (05) :4492-4499

[99] Surface Adsorption and Micelle Formation of Polyoxyethylene-type Nonionic Surfactants in Mixtures of Water and Hydrophilic Imidazolium-type Ionic Liquid [J].

Misono, Takeshi ;

Okada, Kohei ;

Sakai, Kenichi ;

Abe, Masahiko ;

Sakai, Hideki .

JOURNAL OF OLEO SCIENCE, 2016, 65 (06) :499-506

[100] Surface adsorption and aggregate formation of nonionic surfactants in a room temperature ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate (bmimPF6) [J].

Misono, Takeshi ;

Sakai, Hideki ;

Sakai, Kenichi ;

Abe, Masahiko ;

Inoue, Tohru .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 358 (02) :527-533

← 5 6 7 8 9 10 11 12 13 14 →