Solvophobicity and amphiphilic self-assembly in neoteric and nanostructured solvents

被引：21

作者：

Warr, Gregory G. ^{[1
,2
]}

Atkin, Rob ^{[3
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[2] Univ Sydney, Nano Inst, Sydney, NSW 2006, Australia

[3] Univ Western Australia, Sch Mol Sci, Perth, WA 6009, Australia

来源：

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE | 2020年 / 45卷

基金：

澳大利亚研究理事会;

关键词：

Ionic liquids; Amphiphilic; Nanostructure; Scattering; PROTIC IONIC LIQUID; DEEP EUTECTIC SOLVENTS; SPONTANEOUS VESICLE FORMATION; ANGLE NEUTRON-SCATTERING; SODIUM DODECYL-SULFATE; X-RAY-DIFFRACTION; MICELLE FORMATION; ETHYLAMMONIUM NITRATE; NONIONIC SURFACTANTS; PHASE-BEHAVIOR;

D O I：

10.1016/j.cocis.2019.12.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The emergence of ionic liquids and deep eutectics as neoteric solvents that support surfactant self-assembly creates a vast new playing field for creating new forms of soft matter with distinctive properties. Solvophobic self-assembly in ionic liquids and deep eutectics has unique and novel features arising from strong interactions between constituents, high ionic strengths, and the molecular structures of the components, which can induce amphiphilic nanostructure in these nonaqueous solvents. This nanostructure is often reminiscent of microemulsions and sponge phases. Here we review recent new understanding of solvent nanostructure and its effect on self-assembly of surfactants and lipids.

引用

页码：83 / 96

页数：14

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