Preparation of Heterocycles via Visible-Light-Driven Aerobic Selenation of Olefins with Diselenides

被引：72

作者：

Zhang, Qing-Bao ^{[1
]}

Yuan, Pan-Feng ^{[1
]}

Kai, Liang-Lin ^{[1
]}

Liu, Kai ^{[1
]}

Ban, Yong-Liang ^{[1
]}

Wang, Xue-Yang ^{[1
]}

Wu, Li-Zhu ^{[2
]}

Liu, Bang ^{[1
]}

机构：

[1] Lanzhou Univ, State Key Lab Appl Organ Chem, 222 South Tianshui Rd, Lanzhou 730000, Gansu, Peoples R China

[2] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China

来源：

ORGANIC LETTERS | 2019年 / 21卷 / 04期

关键词：

OXAZOLINE-CONTAINING LIGANDS; STEREOSELECTIVE CYCLIZATION; DIPHENYL DISELENIDE; ORGANOSELENIUM; ALKENES; FUNCTIONALIZATION; CHEMISTRY; ION; PHENYLSELENOETHERIFICATION; SELENOFUNCTIONALIZATION;

D O I：

10.1021/acs.orglett.8b03738

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The aerobic dehydrogenative cyclization of alkenes with easily accessible diselenides facilitated by visible light is reported. Notably, the features of this transition-metal-free protocol are pronounced efficiency and practicality, good functional group tolerance, atom economy, and high sustainability, since ambient air and visible light are adequate for the clean construction of five- and six membered heterocycles in yields of up to 98%.

引用

页码：885 / 889

页数：5

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