(μ-Formato-κ2O:O′)bis[dicarbonyl-(η5-cyclopentadienyl)iron(II)]tetrafluoridoborate

被引:0
|
作者
M'thiruaine, Cyprian M. [1 ]
Friedrich, Holger B. [1 ]
Changamu, Evans O. [2 ]
Omondi, Bernard [1 ]
机构
[1] Univ KwaZulu Natal, Sch Chem, ZA-4000 Durban, South Africa
[2] Kenyatta Univ, Dept Chem, Nairobi, Kenya
关键词
COMPLEXES; FORMATE;
D O I
10.1107/S1600536811032764
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the structure of the title compound [Fe-2(C5H5)(2)(CHO2)-(CO)(4)]BF4, each Fe-II atom is coordinated in a pseudooctahedral three-legged piano-stool fashion. The cyclopentadienyl ligand occupies three fac coordination sites while the two carbonyl ligands and formate O atom occupy the remaining three sites.
引用
收藏
页码:M1252 / U888
页数:11
相关论文
共 50 条
  • [41] Application of the Reactions of Ferrocene(Ⅰ) Salts with Bis[dicarbonyl(η ̄5-cyclopentadienyl)iron] and Bis[dicarbonyl(η ̄4-butadiene)cobalt] Complexesto Organic Synthesis
    TAO Ke
    WU Le
    Wurenqimug and YANG Wan-zheng (Department of Cheniistry
    ChemicalResearchinChineseUniversities, 1994, (04) : 280 - 284
  • [42] Bis(acetylsalicylato-κ2O,O′)diaquacadium(II)
    Vásquez-Arciga, H
    Pérez-Benítez, A
    Alvarez-Hernández, A
    Bernès, S
    Méndez-Rojas, MA
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M1621 - M1623
  • [43] Bis(2-methoxyphenolato-κ2O,O′)copper(II)
    Mao, Guo-Zhu
    Nong, Xiu-Lian
    Zhang, Shu Hua
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1208 - +
  • [44] [μ-1κ2O,O′2(η5)-Cyclopentadienylcarboxylato][2(η5)-diphenylphosphinocyclopentadienyl]bis[1,1(η5)tetramethylcyclopentadienyl]iron(II)- titanium(III)
    Mach, K
    Kubista, J
    Císarová, I
    Stepnicka, P
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2002, 58 (02): : m116 - m118
  • [45] Bis[bis(diphenylphosphinoyl)acetonitrile-κ2O,O′]copper(II)
    Sithole, Sicelo V.
    Staples, Richard J.
    Van Zyl, Werner E.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1217 - U583
  • [46] [1,2-bis(dimethylphosphino)ethane]carbonyl(η5-cyclopentadienyl)iron(II) diphenylphosphinoylborate
    Lee, Kajin
    Lough, Alan J.
    Manners, Ian
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M338 - U622
  • [47] {N-[2-(η5-cyclopentadienyl)ethyl]-4-toluenesulfonamido-N,O}(tetrahydrofuran-O)bis(trifluoromethanesulfon-ato-O)titanium(II)
    Lensink, C
    Gainsford, GJ
    Baxter, NI
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2001, 57 : 366 - 367
  • [48] Bis(malonamide-κ2O,O′)bis(nitrato-κO)copper(II)
    Ershov, Mikhail A.
    Skvortsov, Vikenty G.
    Pilchikova, Yulia Yu.
    Koltsova, Olga V.
    Suponitsky, Kyrill Yu.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M3073 - M3075
  • [49] Bis(2-chloro-5-methylpyridine-κN)bis(nitrato-κ2O,O′)copper(II)
    Xuan, RC
    Li, MC
    Wan, YH
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2003, 59 : M462 - M464
  • [50] Bis(μ-4-methylbenzoato-κ2O:O′)bis[aqua(4-methylbenzoato-κ2O,O′)zinc(II)]-bis(μ-4-methylbenzoato-κ2O:O′)bis[(4-methylbenzoato-κO)(nicotinamide-κN)zinc(II)]-water (1/1/2)
    Hokelek, Tuncer
    Ermis, Emel
    Tercan, Baris
    Cimen, Efdal
    Necefoglu, Hacali
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M841 - U1187