(μ-Formato-κ2O:O′)bis[dicarbonyl-(η5-cyclopentadienyl)iron(II)]tetrafluoridoborate

被引：0
|
作者：
M'thiruaine, Cyprian M. [1 ]
Friedrich, Holger B. [1 ]
Changamu, Evans O. [2 ]
Omondi, Bernard [1 ]
机构：
[1] Univ KwaZulu Natal, Sch Chem, ZA-4000 Durban, South Africa
[2] Kenyatta Univ, Dept Chem, Nairobi, Kenya
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
COMPLEXES; FORMATE;
D O I：
10.1107/S1600536811032764
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the structure of the title compound [Fe-2(C5H5)(2)(CHO2)-(CO)(4)]BF4, each Fe-II atom is coordinated in a pseudooctahedral three-legged piano-stool fashion. The cyclopentadienyl ligand occupies three fac coordination sites while the two carbonyl ligands and formate O atom occupy the remaining three sites.
引用
收藏
页码：M1252 / U888
页数：11
相关论文
共 50 条
  • [21] STRUCTURE OF DICARBONYL(ETA-5-CYCLOPENTADIENYL)(O,O'-DIETYL DITHIOPHOSPHATO)IRON(II)
    SANZAPARICIO, J
    MARTINEZCARRERA, S
    GARCIABLANCO, S
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 2009 - 2011
  • [22] STRUCTURE OF (ETA-5-CYCLOPENTADIENYL) (DICARBONYL) (O,O'-DIISOPROPYL DITHIOPHOSPHATO)-IRON(II)
    SANZAPARICIO, J
    MARTINEZCARRERA, S
    GARCIABLANCO, S
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 : 1121 - 1123
  • [23] Bis[dicarbonyl(η5-cyclopentadienyl)ferrio](N,N-diisobutyldithiocarbamato)tin(II)
    Chen, BH
    Li, YZ
    Ma, YX
    Wu, XL
    Li, PR
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M223 - M224
  • [24] μ-Bis(diphenylphosphanyl)borato-κ2P:P′-bis[dicarbonyl(η5-cyclopentadienyl)iron(II)] tetrachloridoferrate(III) chloroform solvate
    Dornhaus, Franz
    Lerner, Hans-Wolfram
    Bolte, Michael
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M835 - U969
  • [25] CRYSTAL AND MOLECULAR-STRUCTURE OF DICARBONYL(ETA-5-CYCLOPENTADIENYL)(FORMATO)IRON(II)
    DARENSBOURG, DJ
    DAY, CS
    FISCHER, MB
    INORGANIC CHEMISTRY, 1981, 20 (10) : 3577 - 3579
  • [26] Crystal structure and Hirshfeld surface analysis of a new mononuclear copper(II) complex: [bis(pyridin-2-yl-κN)amine](formato-κO)(m-hydroxybenzoato-κ2O,O′)copper(II)
    Chaisuriya, Wanassanan
    Chainok, Kittipong
    Wannarit, Nanthawat
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2023, 79 : 1115 - +
  • [27] Bis[μ-η5:η1-2-(cyclopentadienyl)ethoxy]bis[(η5-cyclopentadienyl)(1,2-dimethoxyethane-κO)yttrium]
    Schumann, H
    Dechert, S
    Pestova, II
    Bochkarev, MN
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 : M707 - M709
  • [28] Poly [methylammonium tris(μ2-formato-κ2O:O′)cobalt(II)]
    Boca, M
    Svoboda, I
    Renz, F
    Fuess, H
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 : M631 - M633
  • [29] Poly[dimethylammonium [tris(μ2-formato-κ2O:O′)cadmate(II)]]
    Gao, Shan
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1599 - U1082
  • [30] Dicarbonyl(eta(5)-cyclopentadienyl)(hexamethylenetetramine-kappa N-1) iron(II) tetrafluoridoborate
    M'thiruaine, Cyprian M.
    Friedrich, Holger B.
    Omondi, Bernard
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1077 - +
12345