(μ-Formato-κ2O:O′)bis[dicarbonyl-(η5-cyclopentadienyl)iron(II)]tetrafluoridoborate

被引:0
|
作者
M'thiruaine, Cyprian M. [1 ]
Friedrich, Holger B. [1 ]
Changamu, Evans O. [2 ]
Omondi, Bernard [1 ]
机构
[1] Univ KwaZulu Natal, Sch Chem, ZA-4000 Durban, South Africa
[2] Kenyatta Univ, Dept Chem, Nairobi, Kenya
关键词
COMPLEXES; FORMATE;
D O I
10.1107/S1600536811032764
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the structure of the title compound [Fe-2(C5H5)(2)(CHO2)-(CO)(4)]BF4, each Fe-II atom is coordinated in a pseudooctahedral three-legged piano-stool fashion. The cyclopentadienyl ligand occupies three fac coordination sites while the two carbonyl ligands and formate O atom occupy the remaining three sites.
引用
收藏
页码:M1252 / U888
页数:11
相关论文
共 50 条
  • [1] Bis(η5-cyclopentadienyl)bis(formato-O)-titanium
    Univ of Louisville, Louisville, United States
    Acta Crystallogr Sect C Cryst Struct Commun, Pt 7 (1614-1616):
  • [2] (μ-Ethane-1,2-diamine-κ2 N:N′)bis[dicarbonyl(η5-cyclopentadienyl)iron(II)] bis(tetrafluoridoborate)
    M'thiruaine, Cyprian M.
    Friedrich, Holger B.
    Changamu, Evans O.
    Omondi, Bernard
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M485 - U886
  • [3] Bis(2-arnino-2-thiazolinium) tetra-μ-formato-κ8O:O′-bis[(formato-κO)copper(II)]
    Sieron, Leslaw
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2007, 63 (m199-m200) : M199 - M200
  • [4] [Dicarbonyl(η5-cyclopentadienyl)iron(II)]-μ2-1,3-propanediyl-[dicarbonyl(η5-cyclopentadienyl)ruthenium(II)]
    Friedrich, HB
    Howie, RA
    Onani, MO
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M145 - M147
  • [5] Aqua(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)(formato-κ2O,O′)(formato-κO)cobalt(II) monohydrate
    Ni, Sheng-Liang
    Xia, Ping
    Cao, Feng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M39 - U507
  • [6] Poly[[aqua(μ-4,4′-bipyridyl-κ2N:N′)bis(μ-formato-κ2O:O′)iron(II)] tetrahydrate]
    Jiang, Bin
    Liu, Zhilu
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1189 - +
  • [7] catena-Poly[[[aqua(formato-κO)(1,10-phenanthroline-κ2N,N′)manganese(II)]-μ-formato-κ2O:O′] monohydrate]
    Xu, Wei
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M893 - U722
  • [8] (Formato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)manganese(II) perchlorate
    Zhao, Jun
    Zheng, Xue-Gang
    Hu, Zong-Zhi
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1642 - U1246
  • [9] catena-poly[[[(2,2′-bipyridine-κ2N,N′)(formato-κO)copper(II)]-μ-formato-κ2O:O′] formic acid solvate]
    Lin, Jian-Li
    Hu, Lin-Jing
    Wu, Ling
    Wang, Yuan-Yuan
    Zheng, Yue-Qing
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M2866 - M2868
  • [10] Dicarbonyl(η5-cyclopentadienyl)(trimethylsilylisocyanide)iron(II) trifluoromethanesulfonate
    Nakazawa, H
    Itazaki, M
    Owaribe, M
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M1073 - M1074