Solvothermal syntheses and structural characterization of a series of metal-hydroxycarboxylate coordination polymers

被引：24

作者：

Liu, Jian-Qiang ^{[1
,2
]}

Wang, Yao-Yu ^{[1
,2
]}

Ma, Lu-Fang ^{[1
,2
]}

Zhang, Wei-Hong ^{[1
,2
]}

Zeng, Xi-Rui ^{[3
]}

Shi, Qi-Zhen ^{[1
,2
]}

Peng, Shie-Ming ^{[4
]}

机构：

[1] NW Univ Xian, Dept Chem, Xian 710069, Peoples R China

[2] NW Univ Xian, Shaanxi Key Lab Physinorgan Chem, Xian 710069, Peoples R China

[3] Jinggangshan Univ, Dept Chem, Jian 343009, Jiangxi, Peoples R China

[4] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan

来源：

INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 08期

基金：

中国国家自然科学基金; 高等学校博士学科点专项科研基金;

关键词：

hydroxycarboxylate ligands; crystal structures; solvothermal syntheses; magnetic behavior;

D O I：

10.1016/j.ica.2007.11.036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The combination of transition metal ions with mixed ligands resulted in the formation of three new coordination polymers, {[Co(C4H4O5)(bpe)(H2O)(2)] center dot (0.5bpe)(H2O)}(n) (1), {[Cu(C4H4O6)(bipy)] center dot 5H(2)O}(n) (2) and {[Cu(C4H4O5)(bpa)] center dot 2.5H(2)O}(n) (3) (C4H4O52- = malate dianion, C4H4O62- = tartrate dianion, bpe =1,2-bis(4-pyridyl) ethene, bipy = 2,2'-bipyridine, bpa = 1,2-bis(4-pyridyl) ethane), which were prepared under solvothermal conditions and characterized by single-crystal X-ray diffraction. 1 and 2 feature 1D chain structures. Interestingly, each pair of chains recognizes each other through aromatic pi-pi stacking interactions, generating a zipper-like doublestranded chain in 2. Compound 3 shows 2D 6(3) topology framework with a rectangle-like grid. (C) 2007 Elsevier B. V. All rights reserved.

引用

页码：2327 / 2334

页数：8

共 52 条

[1]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[2]

2-Z

[3] Synthesis, structure and magnetic properties of chiral and nonchiral transition-metal malates [J].

Beghidja, Adel ;

Rabu, Pierre ;

Rogez, Guillaume ;

Welter, Richard .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (29) :7627-7638

[4] Unusual electrochemical and spectroscopic behavior in a ligand-bridged binuclear complex of ruthenium(II): Tetrakis(2,2'-bipyridine)-(mu-2,4,6-tris(2-pyridyl)triazine) diruthenium(II) [J].

Berger, RM ;

Ellis, DD .

INORGANICA CHIMICA ACTA, 1996, 241 (02) :1-4

[5] Alkane oxidation by a carboxylate-bridged dimanganese(III) complex [J].

Blay, G ;

Fernández, I ;

Giménez, T ;

Pedro, JR ;

Ruiz, R ;

Pardo, E ;

Lloret, F ;

Muñoz, MC .

CHEMICAL COMMUNICATIONS, 2001, (20) :2102-2103

[6] THE PREPARATION AND CRYSTAL-STRUCTURE OF AMMONIUM BIS[CITRATO(3-)]CUPRATE(II) [J].

BOTT, RC ;

SAGATYS, DS ;

LYNCH, DE ;

SMITH, G ;

KENNARD, CHL ;

MAK, TCW .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1991, 44 (10) :1495-1498

[7] Supramolecular aggregation of hexameric water clusters into a 2D water polymer containing (H2O)18 holes [J].

Carballo, R ;

Covelo, B ;

Fernández-Hermida, N ;

García-Martínez, E ;

Lago, AB ;

Vázquez, M ;

Vázquez-López, EM .

CRYSTAL GROWTH & DESIGN, 2006, 6 (03) :629-631

[8] Layered metal organosulfides:: hydrothermal synthesis, structure and magnetic behaviour of the spin-canted magnet Co(1,2-(O2C)(S)C6H4) [J].

Cave, D ;

Gascon, JM ;

Bond, AD ;

Teat, SJ ;

Wood, PT .

CHEMICAL COMMUNICATIONS, 2002, (10) :1050-1051

[9] Copper and cadmium coordination polymers of di-3-pyridinylmethanone: Subtle anion effect on the dimensionality of Cd(II) frameworks [J].

Chen, XD ;

Guo, JH ;

Du, M ;

Mak, TCW .

INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (09) :766-768

[10] Syntheses, structures, and magnetic properties of three novel metal-malate-bipyridine coordination polymers with layered and pillared topology [J].

Duan, LM ;

Xie, FT ;

Chen, XY ;

Chen, Y ;

Lu, YK ;

Cheng, P ;

Xu, JQ .

CRYSTAL GROWTH & DESIGN, 2006, 6 (05) :1101-1106

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