Phase-transfer catalyzed asymmetric Darzens reaction of cyclic α-chloro ketones

被引：53

作者：

Arai, S ^{[1
]}

Shirai, Y

Ishida, T

Shioiri, T

机构：

[1] Nagoya City Univ, Fac Pharmaceut Sci, Mizuho Ku, Nagoya, Aichi 4678603, Japan

[2] Osaka Univ Pharmaceut Sci, Osaka 5691041, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 01期

关键词：

D O I：

10.1039/a808321e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic asymmetric Darzens reaction using cyclic cr-chloro ketones promoted by chiral quaternary ammonium salts as a phase-transfer catalyst proceeded smoothly under mild reaction conditions to afford the desired products with reasonable enantioselectivities at room temperature.

引用

页码：49 / 50

页数：2

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