Properties of WZ21 (%wt) alloy processed by a powder metallurgy route

被引:26
作者
Cabeza, Sandra [1 ,2 ]
Garces, Gerardo [2 ]
Perez, Pablo [2 ]
Adeva, Paloma [2 ]
机构
[1] BAM Fed Inst Mat Res & Testing, Dept Nondestruct Testing, D-12205 Berlin, Germany
[2] CSIC, Natl Ctr Met Res CENIM, Dept Met Phys, E-28040 Madrid, Spain
关键词
Magnesium; RE; Microstructure; Creep; Corrosion; ZN-GD ALLOY; MECHANICAL-PROPERTIES; CORROSION BEHAVIOR; MAGNESIUM ALLOYS; CREEP-BEHAVIOR; IN-VIVO; MG; MICROSTRUCTURE; TEMPERATURE; DEFORMATION;
D O I
10.1016/j.jmbbm.2015.02.022
中图分类号
R318 [生物医学工程];
学科分类号
0831 ;
摘要
Microstructure, mechanical properties and corrosion behaviour of WZ21 (%wt) alloy prepared, by a powder metallurgy route from rapidly solidified powders have been studied. Results were compared to those of the same alloy prepared through a conventional route of casting and extrusion. The microstructure of the extruded ingot consisted of alpha-Mg grains and Mg3Zn3Y2 (W-phase) and LPSO-phase particles located at grain boundaries. Moreover, stacking faults were also observed within a-Mg grains. The alloy processed by the powder metallurgy route exhibited a more homogeneous and finer microstructure, with a grain size of 2 mu m. In this case W-phase and Mg24Y5 phase were identified, but not the LPSO-phase. The microstructural refinement induced by the use of rapidly solidified powders strengthened the alloy at room temperature and promoted superplasticity at higher strain rates. Corrosion behaviour in PBS medium evidenced certain physical barrier effect of the almost continuous arrangements of second phases aligned along the extrusion direction in conventionally processed WZ21 alloy, with a stable tendency around 7 mm/year. On the other hand, powder metallurgy processing promoted significant pitting corrosion, inducing accelerated corrosion rate during prolonged immersion times. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:115 / 126
页数:12
相关论文
共 65 条
[1]   The in vivo and in vitro corrosion of high-purity magnesium and magnesium alloys WZ21 and AZ91 [J].
Abidin, Nor Ishida Zainal ;
Rolfe, Barbara ;
Owen, Helen ;
Malisano, Julian ;
Martin, Darren ;
Hofstetter, Joelle ;
Uggowitzer, Peter J. ;
Atrens, Andrej .
CORROSION SCIENCE, 2013, 75 :354-366
[2]   Precipitation reactions in magnesium-rare earth alloys containing Yttrium, Gadolinium or Dysprosium [J].
Apps, PJ ;
Karimzadeh, H ;
King, JF ;
Lorimer, GW .
SCRIPTA MATERIALIA, 2003, 48 (08) :1023-1028
[3]   Influence of Gd on the Corrosion Behavior of AM50 and AZ91D Magnesium Alloys [J].
Arrabal, R. ;
Pardo, A. ;
Merino, M. C. ;
Paucar, K. ;
Mohedano, M. ;
Casajus, P. ;
Garces, G. .
CORROSION, 2012, 68 (05) :398-410
[4]   Effect of Nd on the corrosion behaviour of AM50 and AZ91D magnesium alloys in 3.5 wt.% NaCl solution [J].
Arrabal, R. ;
Pardo, A. ;
Merino, M. C. ;
Mohedano, M. ;
Casajus, P. ;
Paucar, K. ;
Garces, G. .
CORROSION SCIENCE, 2012, 55 :301-312
[5]   A combined neural network and mechanistic approach for the prediction of corrosion rate and yield strength of magnesium-rare earth alloys [J].
Birbilis, N. ;
Cavanaugh, M. K. ;
Sudholz, A. D. ;
Zhu, S. M. ;
Easton, M. A. ;
Gibson, M. A. .
CORROSION SCIENCE, 2011, 53 (01) :168-176
[6]   Effect of yttrium on high temperature strength of magnesium [J].
Chang, SY ;
Nakagaido, T ;
Hong, SK ;
Shin, DH ;
Sato, T .
MATERIALS TRANSACTIONS, 2001, 42 (07) :1332-1338
[7]   The structure of long period stacking/order Mg-Zn-RE phases with extended non-stoichiometry ranges [J].
Egusa, D. ;
Abe, E. .
ACTA MATERIALIA, 2012, 60 (01) :166-178
[8]   Evaluation of short-term effects of rare earth and other elements used in magnesium alloys on primary cells and cell lines [J].
Feyerabend, Frank ;
Fischer, Janine ;
Holtz, Jakob ;
Witte, Frank ;
Willumeit, Regine ;
Druecker, Heiko ;
Vogt, Carla ;
Hort, Norbert .
ACTA BIOMATERIALIA, 2010, 6 (05) :1834-1842
[9]   Effects of rare-earth elements Gd and Y on the solid solution strengthening of Mg alloys [J].
Gao, L. ;
Chen, R. S. ;
Han, E. H. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 481 (1-2) :379-384
[10]   Microstructure evolution in a Mg-15Gd-0.5Zr (wt.%) alloy during isothermal aging at 250°C [J].
Gao, X. ;
He, S. M. ;
Zeng, X. Q. ;
Peng, L. M. ;
Ding, W. J. ;
Nie, J. F. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 431 (1-2) :322-327