Thermochromic properties of low-melting ionic uranyl isothiocyanate complexes

被引：40

作者：

Aoyagi, Noboru ^{[1
,2
]}

Shimojo, Kojiro ^{[1
]}

Brooks, Neil R. ^{[2
]}

Nagaishi, Ryuji ^{[1
]}

Naganawa, Hirochika ^{[1
]}

Van Hecke, Kristof ^{[2
]}

Van Meervelt, Luc ^{[2
]}

Binnemans, Koen ^{[2
]}

Kimura, Takaumi ^{[1
]}

机构：

[1] Japan Atom Energy Agcy, Nucl Sci & Engn Directorate, Ibaraki 3191195, Japan

[2] Katholieke Univ Leuven, Dept Chem, B-3001 Heverlee, Belgium

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 15期

关键词：

URANIUM; COORDINATION; NETWORKS; LIQUIDS;

D O I：

10.1039/c0cc05550f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Temperature-dependent yellow-to-red colour changes of uranyl thiocyanate complexes with 1-alkyl-3-methylimidazolium cations have been studied by different spectroscopic methods and this phenomenon is attributed to changes in the local environment of the uranyl ion, including the coordination number, as well as to cation-anion interactions.

引用

页码：4490 / 4492

页数：3

共 22 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2] Reduction and selective oxo group silylation of the uranyl dication [J].

Arnold, Polly L. ;

Patel, Dipti ;

Wilson, Claire ;

Love, Jason B. .

NATURE, 2008, 451 (7176) :315-U3

[3]

ARUTYUNYAN EG, 1963, ZH STRUKT KHIM, V4, P110

[4] Lanthanides and actinides in ionic liquids [J].

Binnemans, Koen .

CHEMICAL REVIEWS, 2007, 107 (06) :2592-2614

[5] Two- and three-dimensional CuSCN co-ordination networks including new CuSCN structural motifs [J].

Blake, AJ ;

Brooks, NR ;

Champness, NR ;

Crew, M ;

Hanton, LR ;

Hubberstey, P ;

Simon, PC ;

Schröder, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (16) :2813-2817

[6] CRYSTAL-STRUCTURE OF TRIS(2-PYRIDYLTHIO-2-PYRIDINIUM)PENTAISOTHIOCYANATODIOXOURANATE(VI) [J].

BOMBIERI, G ;

FORSELLINI, E ;

GRAZIANI, R ;

PAPPALARDO, GC .

TRANSITION METAL CHEMISTRY, 1979, 4 (02) :70-72

[7] Advances in actinide solid-state and coordination chemistry [J].

Burns, Peter C. ;

Ikeda, Yasuhisa ;

Czerwinski, Ken .

MRS BULLETIN, 2010, 35 (11) :868-876

[8] A propeller-like uranyl metallomesogen [J].

Cardinaels, T ;

Ramaekers, J ;

Guillon, D ;

Donnio, B ;

Binnemans, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (50) :17602-17603

[9] Evidence for alkane coordination to an electron-rich uranium center [J].

Castro-Rodriguez, I ;

Nakai, H ;

Gantzel, P ;

Zakharov, LN ;

Rheingold, AL ;

Meyer, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (51) :15734-15735

[10] PHOTOCHEMICAL AND PHOTOPHYSICAL STUDIES OF TETRANUCLEAR COPPER(I) HALIDE CLUSTERS - AN OVERVIEW [J].

FORD, PC .

COORDINATION CHEMISTRY REVIEWS, 1994, 132 :129-140

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