MWNT/Cellulose Based Nanocomposite Electrodes for Ultrafast Flexible Li-Ion Battery

被引:7
作者
Tripathi, Balram [1 ]
Srivastava, Nisha [2 ]
Sharma, K. B. [2 ]
Zagorskiy, Dmitri [3 ]
Katiyar, Ram S. [1 ]
机构
[1] Univ Puerto Rico, Dept Phys, San Juan, PR 00931 USA
[2] SS Jain Subodh PG Autonomous Coll, Dept Phys, Jaipur 302004, Rajasthan, India
[3] RAS, Ctr Crystallog & Photon, Inst Crystallog, Moscow 83843, Russia
关键词
charge-discharge; FT-IR; MWNT/cellulose; Raman spectroscopy; synthesis; CELLULOSE;
D O I
10.1002/masy.201700042
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In the present study multiwall carbon nanotube (MWNT)/Ethyl cellulose (EC) based nanocomposite electrodes have been fabricated and tested for Li-ion batteries. The insertion of MWNTs of high surface area (140 cm(2)) in ethyl cellulose (EC) polymer has been implicated to obtain flexible and sufficient capacity electrodes. X-ray diffraction spectra showing enhanced crystallinity, Raman spectra showing well orientation of MWNTs in composites, scanning electron microscopy (SEM) images showing MWNTs dominance on surface of the composites, Fourier transform infrared (FT-IR) spectroscopy confirms interfacial interactions and charging-discharging profiles showing enhanced and stable charge storage capacity of composite electrodes. The electrodes of MWNT/EC nanocomposite exhibit charge capacities in between 70-240 mAh/g at charging rate (C/10). These nanocomposite electrodes can be charged up to current of 50 mA/cm(2) with only 5% loss in capacity over 50 subsequent charge and discharge cycles. These composite electrodes are flexible, ultra fast and lightweight.
引用
收藏
页数:4
相关论文
共 36 条
[1]  
Bernhold J., 1996, Applied Physics A: Materials Science Processing, V67, P39
[2]  
Cao Q., 2009, TECH BRIEFS HIST ARC, V4, P18
[3]   A Raman-scattering study on the net orientation of biomacromolecules in the outer epidermal walls of mature wheat stems (Triticum aestivum) [J].
Cao, Yu ;
Shen, Deyan ;
Lu, Yonglai ;
Huang, Yong .
ANNALS OF BOTANY, 2006, 97 (06) :1091-1094
[4]   Self-Assembled Free-Standing Graphite Oxide Membrane [J].
Chen, Chengmeng ;
Yang, Quan-Hong ;
Yang, Yonggang ;
Lv, Wei ;
Wen, Yuefang ;
Hou, Peng-Xiang ;
Wang, Maozhang ;
Cheng, Hui-Ming .
ADVANCED MATERIALS, 2009, 21 (29) :3007-3011
[5]   ALIGNED CARBON NANOTUBE FILMS - PRODUCTION AND OPTICAL AND ELECTRONIC-PROPERTIES [J].
DEHEER, WA ;
BACSA, WS ;
CHATELAIN, A ;
GERFIN, T ;
HUMPHREYBAKER, R ;
FORRO, L ;
UGARTE, D .
SCIENCE, 1995, 268 (5212) :845-847
[6]   FT Raman microscopy of untreated natural plant fibres [J].
Edwards, HGM ;
Farwell, DW ;
Webster, D .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1997, 53 (13) :2383-2392
[7]   Study on the incorporation of photovoltaic systems as an auxiliary power source for hybrid and electric vehicles [J].
Giannouli, M. ;
Yianoulis, P. .
SOLAR ENERGY, 2012, 86 (01) :441-451
[8]   The Li-Ion Rechargeable Battery: A Perspective [J].
Goodenough, John B. ;
Park, Kyu-Sung .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (04) :1167-1176
[9]  
Gozdz A., 2002, 201 M EL SOC, P12
[10]  
Gozdz A, 2003, US Patent, Patent No. [200 30062257 A1, 20030062257]