Trichlorogallium and trialkylgalliums in organic synthesis

被引:41
作者
Yamaguchi, Masahiko [1 ]
Nishimura, Yoshio [1 ]
机构
[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Dept Organ Chem, Sendai, Miyagi 980, Japan
关键词
D O I
10.1039/b710136h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Organic gallium compounds formed by the interactions of organic compounds with trichlorogallium or trialkylgalliums exhibit various reactivities, and their use in organic synthesis is described.
引用
收藏
页码:35 / 48
页数:14
相关论文
共 91 条
[1]   GaCl3 promoted one-step α,α-diethynylation and α,α-diethenylation reactions of silyl enol ethers [J].
Amemiya, R ;
Miyake, Y ;
Yamaguchi, M .
TETRAHEDRON LETTERS, 2006, 47 (11) :1797-1800
[2]   GaCl3 in organic synthesis [J].
Amemiya, R ;
Yamaguchi, M .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2005, 2005 (24) :5145-5150
[3]   One-step synthesis of triethynylvinylmethanes and tetraethynylmethanes by GaCl3-promoted diethynylation of 1,4-enynes and 1,4-diynes [J].
Amemiya, R ;
Suwa, K ;
Toriyama, J ;
Nishimura, Y ;
Yamaguchi, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (23) :8252-8253
[4]   GaCl3-catalyzed α-ethenylation reaction of ketone [J].
Amemiya, R ;
Nishimura, Y ;
Yamaguchi, M .
SYNTHESIS-STUTTGART, 2004, (09) :1307-1314
[5]   GaCl3-catalyzed ortho-ethynylation reaction of N-benzylanilines [J].
Amemiya, R ;
Fujii, A ;
Yamaguchi, M .
TETRAHEDRON LETTERS, 2004, 45 (22) :4333-4335
[6]   Sequential carbometalation/elimination reaction takes place between gallium enolate and chloroethyne [J].
Amemiya, R ;
Fujii, A ;
Arisawa, M ;
Yamaguchi, M .
CHEMISTRY LETTERS, 2003, 32 (03) :298-299
[7]   GaCl3-catalyzed α-ethynylation reaction of silyl enol ethers [J].
Amemiya, R ;
Fujii, A ;
Arisawa, M ;
Yamaguchi, M .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 686 (1-2) :94-100
[8]  
AMEMIYA R, IN PRESS LEWIS ACIS
[9]   Gallium trichloride-catalyzed exhaustive α-ethynylation reaction of 1-silylacetylenes [J].
Amemiya, Ryo ;
Yamaguchi, Masahiko .
ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (07) :1011-1014
[10]  
[Anonymous], MAIN GROUP METALS OR