Nitrogen doped carbon nanofiber derived from polypyrrole functionalized polyacrylonitrile for applications in lithium-ion batteries and oxygen reduction reaction

被引：48

作者：

Guo, Jiayi ^{[1
]}

Liu, Jiaqi ^{[1
]}

Dai, Henghan ^{[1
]}

Zhou, Rui ^{[1
]}

Wang, Tianying ^{[1
]}

Zhang, Cuicui ^{[1
]}

Ding, Shan ^{[1
]}

Wang, Heng-guo ^{[1
]}

机构：

[1] Changchun Univ Sci & Technol, Sch Mat Sci & Engn, Changchun 130022, Jilin, Peoples R China

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2017年 / 507卷

基金：

中国国家自然科学基金;

关键词：

Nitrogen dope; Carbon materials; Flexible electrode; Lithium-ion batteries; Oxygen reduction reaction; PERFORMANCE ANODE MATERIAL; ELECTROCHEMICAL PERFORMANCE; POROUS CARBON; MULTIFUNCTIONAL APPLICATIONS; FACILE SYNTHESIS; ENERGY-STORAGE; GRAPHENE; COMPOSITES; FABRICATION; EFFICIENT;

D O I：

10.1016/j.jcis.2017.07.117

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nitrogen doped carbon nanofiber films (NCNFs) is successfully synthesized via the carbonization of polypyrrole (PPY) functionalized electrospun polyacrylonitrile (PAN) nanofibers. Benefitting from the nitrogen-doped one-dimensional (1D) nanostructure, the as-obtained NCNFs show multifunctional applications as electrode materials for lithium ion batteries (LIBs) and catalysts for oxygen reduction reaction (ORR). For LIB application, the obtained NCNFs could be directly used as flexible, free-standing and binder-free electrode, which exhibits high specific capacity up to 698.9 mAh g(-1) (higher than that of carbon nanofiber derived from PAN), long life over 160 cycles, and good rate capability (148.8 mAh g(-1) at 2 A g(-1)). In addition, a preliminary ORR catalytic activity study has demonstrated that the NCNFs exhibit good catalytic activity. Therefore, these properties endorse NCNFs as auspicious candidates for both LIBs and ORR. (C) 2017 Elsevier Inc. All rights reserved.

引用

页码：154 / 161

页数：8

共 45 条

[1] Building better batteries [J].

Armand, M. ;

Tarascon, J. -M. .

NATURE, 2008, 451 (7179) :652-657

[2] Non-precious metal doped carbon nanofiber air-cathode for Microbial Fuel Cells application: Oxygen reduction reaction characterization and long-term validation [J].

Bosch-Jimenez, Pau ;

Martinez-Crespiera, Sandra ;

Amantia, David ;

Della Pirriera, Monica ;

Forns, Isabel ;

Shechter, Ronen ;

Borras, Eduard .

ELECTROCHIMICA ACTA, 2017, 228 :380-388

[3] Electrochemical properties of nitrogen-doped carbon nanotube anode in Li-ion batteries [J].

Bulusheva, L. G. ;

Okotrub, A. V. ;

Kurenya, A. G. ;

Zhang, Hongkun ;

Zhang, Huijuan ;

Chen, Xiaohong ;

Song, Huaihe .

CARBON, 2011, 49 (12) :4013-4023

[4] Nitrogen-rich Fe-N-C materials derived from polyacrylonitrile as highly active and durable catalysts for the oxygen reduction reaction in both acidic and alkaline electrolytes [J].

Chen, J. L. ;

Li, W. B. ;

Xu, B. Q. .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 502 :44-51

[5] Nitrogen-Doped Carbon Nanocages as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction [J].

Chen, Sheng ;

Bi, Jiyu ;

Zhao, Yu ;

Yang, Lijun ;

Zhang, Chen ;

Ma, Yanwen ;

Wu, Qiang ;

Wang, Xizhang ;

Hu, Zheng .

ADVANCED MATERIALS, 2012, 24 (41) :5593-5597

[6] Soft-Templated Mesoporous Carbon-Carbon Nanotube Composites for High Performance Lithium-ion Batteries [J].

Guo, Bingkun ;

Wang, Xiqing ;

Fulvio, Pasquale F. ;

Chi, Miaofang ;

Mahurin, Shannon M. ;

Sun, Xiao-Guang ;

Dai, Sheng .

ADVANCED MATERIALS, 2011, 23 (40) :4661-+

[7] Fabrication of carbon nanofiber-driven electrodes from electrospun polyacrylonitrile/polypyrrole bicomponents for high-performance rechargeable lithium-ion batteries [J].

Ji, Liwen ;

Yao, Yingfang ;

Toprakci, Ozan ;

Lin, Zhan ;

Liang, Yinzheng ;

Shi, Quan ;

Medford, Andrew J. ;

Millns, Christopher R. ;

Zhang, Xiangwu .

JOURNAL OF POWER SOURCES, 2010, 195 (07) :2050-2056

[8] In-Situ Encapsulation of Nickel Particles in Electrospun Carbon Nanofibers and the Resultant Electrochemical Performance [J].

Ji, Liwen ;

Lin, Zhan ;

Medford, Andrew J. ;

Zhang, Xiangwu .

CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (41) :10718-10722

[9] Porous carbon nanofibers from electrospun polyacrylonitrile/SiO2 composites as an energy storage material [J].

Ji, Liwen ;

Lin, Zhan ;

Medford, Andrew J. ;

Zhang, Xiangwu .

CARBON, 2009, 47 (14) :3346-3354

[10] Generation of activated carbon nanofibers from electrospun polyacrylonitrile-zinc chloride composites for use as anodes in lithium-ion batteries [J].

Ji, Liwen ;

Zhang, Xiangwu .

ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (03) :684-687

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