A novel chemiluminescence from the reaction of dioxiranes with alkanes. Proposed mechanism of oxygen-transfer chemiluminescence

被引：11

作者：

Kazakov, DV ^{[1
]}

Barzilova, AB ^{[1
]}

Kazakov, VP ^{[1
]}

机构：

[1] RAS, Ufa Sci Ctr, Inst Organ Chem, Ufa 450054, Russia

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 02期

关键词：

D O I：

10.1039/b008315l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidation of adamantane and 2,3-dimethylbutane by methyl(trifluoromethyl)dioxirane is accompanied by chemiluminescence (CL); formation of the emitter of CL, triplet excited trifluoropropanone, is proposed to occur via a concerted oxenoid mechanism of oxygen insertion into C-H bond of the hydrocarbons.

引用

页码：191 / 192

页数：2

共 25 条

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