Design of a Highly-Stable Pillar-Layer Zinc(II) Porous Framework for Rapid, Reversible, and Multi-Responsive Luminescent Sensor in Water

被引：161
作者：
He, Hongming [1 ]
Zhu, Qian-Qian [1 ]
Li, Cheng-Peng [1 ]
Du, Miao [1 ]
机构：
[1] Tianjin Normal Univ, Coll Chem, MOE Key Lab Inorgan Organ Hybrid Funct Mat Chem, Tianjin Key Lab Struct & Performance Funct Molecu, Tianjin 300387, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2019年 / 19卷 / 02期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORK; FLUORESCENT SENSOR; SELECTIVE DETECTION; CR(VI) IONS; ANTIBIOTICS; FE(III); MOF; CHEMOSENSOR; CLUSTERS; CR(III);
D O I：
10.1021/acs.cgd.8b01271
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hard-soft-acid-base (HSAB) and dual-ligand strategies have been used to construct a pillar-layer luminescent metal-organic framework (MOF) {[Zn-2(TRZ)(2)(DBTDC-O-2)]center dot DMAc}(n) (1), in which H2DBTDC-O-2 = S,S-dioxodibenzothiophen-3,7-dicarboxylic acid and HTRZ = 1,2,4-triazole. Thanks to its high stability in water and quadrangle microporous channels, MOF 1 can be served as a platform of recyclable multi-responsive luminescent sensor for Fe3+, Al3+,SiF62-,Cr2O72-, nitrofurantoin (NFT), and nitrofurazone (NFZ) in water. This is the first MOF-based sensor for detecting SiF62- anion via luminescent enhancement effect. Significantly, 1 also represents a unique example to probe NFZ or NFT by using transition metal MOFs in water, which exhibits the most sensitive sensing ability for NFZ (K-sv = 5.2 X 10(4) M-1) and NFT (K-sv = 1.8 x 10(5) M-1) via luminescent quenching.
引用
收藏
页码：694 / 703
页数：10
相关论文
共 56 条
[41]   Heavy metal contamination and human health risk assessment in drinking water from shallow groundwater wells in an agricultural area in Ubon Ratchathani province, Thailand [J].
Wongsasuluk, Pokkate ;
Chotpantarat, Srilert ;
Siriwong, Wattasit ;
Robson, Mark .
ENVIRONMENTAL GEOCHEMISTRY AND HEALTH, 2014, 36 (01) :169-182
[42]   Fluorescent chemosensors: the past, present and future [J].
Wu, Di ;
Sedgwick, Adam C. ;
Gunnlaugsson, Thorfinnur ;
Akkaya, Engin U. ;
Yoon, Juyoung ;
James, Tony D. .
CHEMICAL SOCIETY REVIEWS, 2017, 46 (23) :7105-7123
[43]   Tetraphenylethylene Immobilized Metal-Organic Frameworks: Highly Sensitive Fluorescent Sensor for the Detection of Cr2O72- and Nitroaromatic Explosives [J].
Wu, Xiao-Xia ;
Fu, Hong-Ru ;
Han, Min-Le ;
Zhou, Zhan ;
Ma, Lu-Fang .
CRYSTAL GROWTH & DESIGN, 2017, 17 (11) :6041-6048
[44]   Four new metal-organic frameworks constructed from H2DBTDC-O2 (H2DBTDC-O2 = dibenzothiophene-5,5′-dioxide-3,7-dicarboxylic acid) ligand with guest-responsive photoluminescence [J].
Xiong, Shunshun ;
Wang, Sujing ;
Tang, Xinjun ;
Wang, Zhiyong .
CRYSTENGCOMM, 2011, 13 (05) :1646-1653
[45]   Recent progress in two-dimensional inorganic quantum dots [J].
Xu, Yuanhong ;
Wang, Xiaoxia ;
Zhang, Wen Ling ;
Lv, Fan ;
Guo, Shaojun .
CHEMICAL SOCIETY REVIEWS, 2018, 47 (02) :586-625
[46]   Lanthanide Metal-Organic Frameworks Based on Octahedral Secondary Building Units: Rare Net Topology and Luminescence [J].
Yan, Li ;
Yue, Qi ;
Jia, Qin-Xiang ;
Lemercier, Gilles ;
Gao, En-Qing .
CRYSTAL GROWTH & DESIGN, 2009, 9 (07) :2984-2987
[47]   A metal-organic framework as a "turn on" fluorescent sensor for aluminum ions [J].
Yu, Mei-Hui ;
Hu, Tong-Liang ;
Bu, Xian-He .
INORGANIC CHEMISTRY FRONTIERS, 2017, 4 (02) :256-260
[48]   Design of Pore Size and Functionality in Pillar-Layered Zn-Triazolate-Dicarboxylate Frameworks and Their High CO2/CH4 and C2 Hydrocarbons/CH4 Selectivity [J].
Zhai, Quan-Guo ;
Bai, Ni ;
Li, Shu'ni ;
Bu, Xianhui ;
Feng, Pingyun .
INORGANIC CHEMISTRY, 2015, 54 (20) :9862-9868
[49]   A Lanthanide MOF Thin-Film Fixed with Co3O4 Nano-Anchors as a Highly Efficient Luminescent Sensor for Nitrofuran Antibiotics [J].
Zhang, Feng ;
Yao, Hua ;
Chu, Tianshu ;
Zhang, Gaowei ;
Wang, Yi ;
Yang, Yangyi .
CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (43) :10293-10300
[50]   A Water-Stable 3D Luminescent Metal-Organic Framework Based on Heterometallic [Eu6IIIZnII] Clusters Showing Highly Sensitive, Selective, and Reversible Detection of Ronidazole [J].
Zhang, Qingfu ;
Lei, Mingyuan ;
Yan, Hui ;
Wang, Jinyun ;
Shi, Yang .
INORGANIC CHEMISTRY, 2017, 56 (14) :7610-7614
123456