Recent Advances in the Synthesis of Natural 2-Deoxy-β-glycosides

被引：83

作者：

Borovika, Alina ^{[1
]}

Nagorny, Pavel ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 2012年 / 31卷 / 4-6期

关键词：

2-deoxy-beta-glycosides; Glycosylation; Synthesis; Natural products; PALLADIUM-CATALYZED GLYCOSYLATION; GLYCOSIDE BOND SYNTHESIS; DE-NOVO SYNTHESIS; HIGHLY STEREOSELECTIVE-SYNTHESIS; CHAPERONE DOWN-REGULATOR; BETA-D-MANNOPYRANOSIDES; LANDOMYCIN-A; GOLD(I)-CATALYZED GLYCOSYLATION; ORTHO-ALKYNYLBENZOATES; STEREOCONTROLLED SYNTHESIS;

D O I：

10.1080/07328303.2012.663432

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

This report provides an overview of the recent synthetic efforts directed toward the assembly of complex 2-deoxy-beta-glycoside-containing natural products landomycin A, apoptolidin A, digitoxin, lomaiviticin A, incednine, and versipelostatin. In particular, the intention of this review is to cover the work published since the earlier reports on this topic by Lowary and Hou (2009) and Franck and Marzabadi (2000).

引用

页码：255 / 283

页数：29

共 133 条

[71] Assembly of Digitoxin by Gold(I)-Catalyzed Glycosidation of Glycosyl o-Alkynylbenzoates [J].