Synthesis of TiO2 with Hierarchical Porosity for the Photooxidation of Propene

被引:18
作者
Fernandez-Catala, Javier
Cano-Casanova, Laura
Angeles Lillo-Rodenas, Maria
Berenguer-Murcia, Angel
Cazorla-Amoros, Diego [1 ]
机构
[1] Alicante Univ, Dept Inorgan Chem, Ap 99, E-03080 Alicante, Spain
来源
MOLECULES | 2017年 / 22卷 / 12期
关键词
TiO2; hierarchical porosity; photocatalytic activity; propene; PHOTOCATALYTIC ACTIVITY; PHASE; OXIDATION; NANOPARTICLES; STABILITY; SMOKE; WATER; AREA; HCL;
D O I
10.3390/molecules22122243
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The elimination of volatile organic compounds (VOCs) at low concentration is a subject of great interest because these compounds are very harmful for the environment and human health. In this work, we have developed a synthesis methodology of TiO2 that allows obtaining meso-macroporous materials with hierarchical porosity and with high thermal stability for their application as photocatalysts in the removal of VOCs, specifically propene. The materials synthesized in this work were characterized by Scanning electron microscope (SEM), Transmission electron microscopy (TEM), powder X-ray diffraction (XRD), Thermogravimetric Analysis (TG), and nitrogen adsorption. It is observed that the samples calcined at 250 degrees C and 500 degrees C present a high photoactivity for the photooxidation of propene, which is similar to the benchmark material P25 (commercial TiO2). Moreover, the textural properties are better than those for P25, indicating that the samples are interesting for the preparation of photocatalysts with different conformations, such as in the form of coatings and fillings in different size scales.
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页数:16
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