Catalytic reduction of 4-nitrophenol using CuO@Na2Ti(PO4)(2).H2O

被引:4
|
作者
Mahaulpatha, Bishenka H. [1 ]
Palliyaguru, Lalinda [1 ]
Jayawardene, Savidya [2 ]
Shimomura, Masaru [2 ]
Baltrusaitis, Jonas [3 ]
Jayaweera, Pradeep M. [1 ]
机构
[1] Univ Sri Jayewardenepura, Dept Chem, Nugegoda, Sri Lanka
[2] Shizuoka Univ, Grad Sch Integrated Sci & Technol, Dept Engn, Hamamatsu, Shizuoka, Japan
[3] Lehigh Univ, Dept Chem & Biomol Engn, Bethlehem, PA 18015 USA
来源
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING | 2022年 / 57卷 / 01期
基金
美国国家科学基金会;
关键词
4-nitrophenol; cupric oxide; sodium titanium phosphate; catalytic reduction; GENERALIZED GRADIENT APPROXIMATION; TOTAL-ENERGY CALCULATIONS; PHOTOCATALYTIC ACTIVITY; ION-EXCHANGE; TITANIUM PHOSPHATE; DEGRADATION; NANOPARTICLES; MECHANISM; TIO2; CUO;
D O I
10.1080/10934529.2022.2031842
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This article presents the synthesis, property characterization and catalytic application of CuO-supported disodium titanium phosphate, (CuO@Na2Ti(PO4)(2).H2O) for the reduction of industrial pollutant 4-nitrophenol (4-NP). A simple hydrothermal route was developed to synthesize CuO@Na2Ti(PO4)(2).H2O catalyst (CuO@Na2TiP) from beach sand ilmenite. The prepared CuO@Na2TiP was characterized using X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, X-ray photoelectron spectroscopy, and nitrogen adsorption-desorption isotherms. The catalyst 12 wt.% CuO@Na2TiP showed the fastest reduction kinetics for 4-NP.
引用
收藏
页码:65 / 79
页数:15
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