Formation thermodynamics of mixed-ligand complexes of mercury(II) ethylenediaminetetraacetate with amine ligands in aqueous solution

被引：0

作者：

Pyreu, DF ^{[1
]}

Titova, ES ^{[1
]}

Kozlovskii, EV ^{[1
]}

机构：

[1] Ivanovo State Univ, Ivanovo 153025, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 50卷 / 10期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermodynamic parameters (log K, Delta(r)H, and Delta(r)S) of the reactions HgEdta(2-) + L = HgEdtaL(2-) (L = NH3, NH2(CH2)(2)NH2, C2H5N, NH2CH2COO-) were determined at 298.15 K and I = 0.5 (NaClO4) by calorimetry and pH-metry. The most likely coordination mode of the extra and chelating ligands in the mixed-ligand complexes is discussed.

引用

页码：1647 / 1649

页数：3

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