Energetic salts of substituted 1,2,4-triazolium and tetrazolium 3,5-dinitro-1,2,4-triazolates

被引：92
作者：
Xue, H [1 ]
Twamley, B [1 ]
Shreeve, JM [1 ]
机构：
[1] Univ Idaho, Dept Chem, Moscow, ID 83843 USA
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2005年 / 15卷 / 34期
关键词：
D O I：
10.1039/b507996a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Energetic salts comprised of substituted 1,2,4-triazolium and tetrazolium cations and 3,5-dinitro-1,2,4-triazolate anion were synthesized and characterized. The structure of 4,5-dimethyl-1-aminotetrazolium 3,5-dinitro-1,2,4-triazolate (16) was confirmed by X-ray analysis. Based on experimentally obtained heats of combustion, these materials have calculated heats of formation ranging from Delta H-f degrees = 118 (2) to 778 kJ mol(-1) (10) with densities > 1.5 g cm(-3). Salts, 2, 4, 7, 9 and 10, fall into the ionic liquid class (mp < 100 degrees C).
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页码：3459 / 3465
页数：7
相关论文
共 56 条
[21]   Derivatives of 1,5-diamino-1H-tetrazole:: A new family of energetic heterocyclic-based salts [J].
Gálvez-Ruiz, JC ;
Holl, G ;
Karaghiosoff, K ;
Klapotke, TM ;
Lohnwitz, K ;
Mayer, P ;
Noth, H ;
Polborn, K ;
Rohbogner, CJ ;
Suter, M ;
Weigand, JJ .
INORGANIC CHEMISTRY, 2005, 44 (12) :4237-4253
[22]   Guanidinium-based ionic liquids [J].
Gao, Y ;
Arritt, SW ;
Twamley, B ;
Shreeve, JM .
INORGANIC CHEMISTRY, 2005, 44 (06) :1704-1712
[23]   Calculation of the detonation velocities and detonation pressures of dinitrobiuret (DNB) and diaminotetrazolium nitrate (HDAT-NO3) [J].
Geith, J ;
Klapötke, TM ;
Weigand, J ;
Holl, G .
PROPELLANTS EXPLOSIVES PYROTECHNICS, 2004, 29 (01) :3-8
[24]   A new class of flexible energetic salts: The crystal structures of the ammonium, lithium, potassium, and cesium salts of dinitramide [J].
Gilardi, R ;
FlippenAnderson, J ;
George, C ;
Butcher, RJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (40) :9411-9416
[25]   Synthesis, structure, molecular orbital calculations and decomposition mechanism for tetrazolylazide CHN7, its phenyl derivative PhCN7 and tetrazolylpentazole CHN9 [J].
Hammerl, A ;
Klapötke, TM ;
Mayer, P ;
Weigand, JJ ;
Holl, G .
PROPELLANTS EXPLOSIVES PYROTECHNICS, 2005, 30 (01) :17-26
[26]   Synthesis, structure, molecular orbital and valence bond calculations for tetrazole azide, CHN7 [J].
Hammerl, A ;
Klapötke, TM ;
Nöth, H ;
Warchhold, M ;
Holl, G .
PROPELLANTS EXPLOSIVES PYROTECHNICS, 2003, 28 (04) :165-173
[27]  
Hammerl A, 2002, EUR J INORG CHEM, P834
[28]   [N2H5]+2[N4C-N=N-CN4]2-:: A new high-nitrogen high-energetic material [J].
Hammerl, A ;
Klapötke, TM ;
Nöth, H ;
Warchhold, M ;
Holl, G ;
Kaiser, M ;
Ticmanis, U .
INORGANIC CHEMISTRY, 2001, 40 (14) :3570-3575
[29]   X-RAY CRYSTALLOGRAPHY - A FAST, FIRST-RESORT ANALYTICAL TOOL [J].
HOPE, H .
PROGRESS IN INORGANIC CHEMISTRY, VOL 41, 1994, 41 :1-19
[30]   Characterization of ADN and ADN-based propellants [J].
Jones, DEG ;
Kwok, QSM ;
Vachon, M ;
Badeen, C ;
Ridley, W .
PROPELLANTS EXPLOSIVES PYROTECHNICS, 2005, 30 (02) :140-147
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