Lanthanum does form stable molecular compounds in the+2 oxidation state

被引：213

作者：

Hitchcock, Peter B. ^{[1
]}

Lappert, Michael F. ^{[1
]}

Maron, Laurent ^{[2
]}

Protchenko, Andrey V. ^{[1
]}

机构：

[1] Univ Sussex, Dept Chem, Brighton BN1 9QJ, E Sussex, England

[2] Univ Toulouse 3, Lab Nanophys, INSA, F-31077 Toulouse, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 08期

关键词：

cerium; cyclopentadienyl ligands; density functional calculations; lanthanum; reduction;

D O I：

10.1002/anie.200704887

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Getting down to business: Reduction of the La III tricyclopentadienide complex [LaCp″3] (Cp″ = η5-1,3-(SiMe3)2C5H 3) by K and [18]crown-6 or [2,2,2]cryptand produced thermally stable mononuclear crystalline lanthanate(II) salts. The La +2 oxidation state in these complexes was confirmed both in solution (EPR) and the solid state (EPR, SQUID, X-ray diffraction) and was supported by a computational study. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1488 / 1491

页数：4

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