Synthesis and Characterization of Microporous ZrO2 Membranes for Gas Permeation at 200°C

被引：28

作者：

Casado Coterillo, Clara ^{[1
,3
,4
]}

Yokoo, Tsuyoshi ^{[2
,4
]}

Yoshioka, Tomohisa ^{[2
,4
]}

Tsuru, Toshinori ^{[2
,4
]}

Asaeda, Masashi ^{[2
,4
]}

机构：

[1] Hiroshima Univ, Dept Chem Engn, Higashihiroshima, Japan

[2] Hiroshima Univ, Dept Chem Engn, Higashihiroshima, Japan

[3] Univ Zaragoza, Dept Chem & Environm Engn, Zaragoza 50018, Spain

[4] Hiroshima Univ, Dept Chem Engn, Higashihiroshima 724, Japan

来源：

SEPARATION SCIENCE AND TECHNOLOGY | 2011年 / 46卷 / 08期

基金：

日本学术振兴会;

关键词：

characterization; gas permeation; microporous membrane; microporous zirconia; sol-gel process; ZEOLITE MEMBRANES; INORGANIC MEMBRANE; CARBON-DIOXIDE; CO2; SORPTION; SEPARATION; PERMPOROMETRY; DEPOSITION; FILMS;

D O I：

10.1080/01496395.2011.556098

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of gas separation membranes able to work at high temperatures require robust and thin ceramic layers. In this work, zirconia membranes have been prepared by the sol-gel method, following the colloidal sol route. The microporosity and crystallinity of the ZrO2 material was tested by N2 adsorption and XRD. The derived active zirconia layers were defect-free as seen by SEM. The optimum firing temperature range was set in the range 400-500 degrees C. He, H2, CO2, N2 gas permeation was conducted at temperatures up to 200 degrees C. High permeances were obtained and the microporosity of the zirconia layer was confirmed.

引用

页码：1224 / 1230

页数：7

共 31 条

[1] Separation of CO2 from flue gas:: A review [J].

Aaron, D ;

Tsouris, C .

SEPARATION SCIENCE AND TECHNOLOGY, 2005, 40 (1-3) :321-348

[2] Surface modification of mesoporous membranes by fluoro-silane coupling reagent for CO2 separation [J].

Abidi, N ;

Sivade, A ;

Bourret, D ;

Larbot, A ;

Boutevin, B ;

Guida-Pietrasanta, F ;

Ratsimihety, A .

JOURNAL OF MEMBRANE SCIENCE, 2006, 270 (1-2) :101-107

[3] Synthesis of inorganic membrane by sol-gel process [J].

Agoudjil, N. ;

Kermadi, S. ;

Larbot, A. .

DESALINATION, 2008, 223 (1-3) :417-424

[4] Permeation properties of a thin silicalite-1 (MFI) membrane [J].

Algieri, C ;

Bernardo, P ;

Golemme, G ;

Barbieri, G ;

Drioli, E .

JOURNAL OF MEMBRANE SCIENCE, 2003, 222 (1-2) :181-190

[5] Separation of inorganic/organic gas mixtures by porous silica membranes [J].

Asaeda, M ;

Yamasaki, S .

SEPARATION AND PURIFICATION TECHNOLOGY, 2001, 25 (1-3) :151-159

[6] CO2 sorption of a thin silica layer determined by spectroscopic ellipsometry [J].

Benes, NE ;

Spijksma, G ;

Verweij, H ;

Wormeester, H ;

Poelsema, B .

AICHE JOURNAL, 2001, 47 (05) :1212-1218

[7] PERMPOROMETRY STUDY ON THE SIZE DISTRIBUTION OF ACTIVE PORES IN POROUS CERAMIC MEMBRANES [J].

CAO, GZ ;

MEIJERINK, J ;

BRINKMAN, HW ;

BURGGRAAF, AJ .

JOURNAL OF MEMBRANE SCIENCE, 1993, 83 (02) :221-235

[8] Zeolite membranes -: state of their development and perspective [J].

Caro, J ;

Noack, M ;

Kölsch, P ;

Schäfer, R .

MICROPOROUS AND MESOPOROUS MATERIALS, 2000, 38 (01) :3-24

[9] Preparation of crack-free ZrO2 membrane on Al2O3 support with ZrO2-Al2O3 composite intermediate layers [J].

Chang, QB ;

Zhang, L ;

Liu, XQ ;

Peng, DK ;

Meng, GY .

JOURNAL OF MEMBRANE SCIENCE, 2005, 250 (1-2) :105-111

[10] Synthesis and characterization of microporous silica-alumina membranes [J].

Cheraitia, Abdallah ;

Ayral, Andre ;

Julbe, Anne ;

Rouessac, Vincent ;

Satha, Hamid .

JOURNAL OF POROUS MATERIALS, 2010, 17 (03) :259-263

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