Effect of microalloying with Ca on the microstructure and mechanical properties of Mg-6 mass%Zn alloys

被引:122
作者
Du, Y. Z. [1 ,2 ]
Qiao, X. G. [1 ]
Zheng, M. Y. [1 ]
Wang, D. B. [3 ]
Wu, K. [1 ]
Golovin, I. S. [4 ]
机构
[1] Harbin Inst Technol, Sch Mat Sci & Engn, POB 433, Harbin 150001, Peoples R China
[2] Xian Univ Technol, Sch Mat Sci & Engn, Xian 710048, Peoples R China
[3] Maanshan Steel Co LTD, Res & Technol Ctr, Maanshan 243000, Peoples R China
[4] Natl Univ Sci & Technol MISIS, Leninsky Ave 4, Moscow 119049, Russia
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Mg-Zn-Ca alloy; Microalloying; Microstructure; Precipitates; Mechanical properties; DUCTILE MAGNESIUM ALLOYS; STRETCH FORMABILITY; ROOM-TEMPERATURE; WROUGHT MAGNESIUM; HIGH-STRENGTH; THERMAL-STABILITY; MN ALLOYS; AS-CAST; TEXTURE; CALCIUM;
D O I
10.1016/j.matdes.2016.03.025
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The Mg-6 mass%Zn alloys microalloyed with different amounts of Ca were cast and extruded. The second phase in the as-cast Mg-6Zn alloy is Mg4Zn7, which is replaced by Ca2Mg6Zn3 with an increase of Ca addition. Microalloying by Ca affects the grain size, dynamic recrystallization, and dynamic precipitation of Mg-6Zn alloys during extrusion. The Ca addition inhibits dynamic recrystallization and grain growth clue to the pinning effect of fine precipitates, giving rise to fine dynamic recrystallized grains. A large amount of precipitates is observed in the Ca containing alloys after extrusion. Ca effectively improves strength of the as-extruded Mg-6Zn alloy, which is mainly attributed to refined dynamic recrystallized grains, dense precipitates, and deformed regions with high-density dislocations and strong basal texture. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:285 / 293
页数:9
相关论文
共 64 条
[21]  
Humphreys F.J., 2005, RECRYSTALLIZATION RE
[22]   NUCLEATION OF RECRYSTALLIZATION AT 2ND PHASE PARTICLES IN DEFORMED ALUMINUM [J].
HUMPHREYS, FJ .
ACTA METALLURGICA, 1977, 25 (11) :1323-1344
[23]   Second phase formation in melt-spun Mg-Ca-Zn alloys [J].
Jardim, PM ;
Solórzano, G ;
Vander Sande, JB .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2004, 381 (1-2) :196-205
[24]   Effects of calcium and rare-earth elements on the microstructure and tension-compression yield asymmetry of ZEK100 alloy [J].
Kamrani, S. ;
Fleck, C. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2014, 618 :238-243
[25]  
Kim D. W., 2013, METALL MATER TRANS A, P1
[26]   Effect of calcium content on the microstructural evolution and mechanical properties of wrought Mg-3Al-1Zn alloy [J].
Kim, Jeoung Han ;
Kang, Na Eun ;
Yim, Chang Dong ;
Kim, Byoung Kee .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2009, 525 (1-2) :18-+
[27]   Key factor influencing the ignition resistance of magnesium alloys at elevated temperatures [J].
Kim, Young Min ;
Yim, Chang Dong ;
Kim, Ha Sik ;
You, Bong Sun .
SCRIPTA MATERIALIA, 2011, 65 (11) :958-961
[28]   Effect of Ca additions on the microstructure, thermal stability and mechanical properties of a cast AM60 magnesium alloy [J].
Kondori, B. ;
Mahmudi, R. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2010, 527 (7-8) :2014-2021
[29]   The influence of calcium and cerium mischmetal on the microstructural evolution of Mg-3Al-1Zn during extrusion and resulting mechanical properties [J].
Laser, T. ;
Hartig, Ch. ;
Nuernberg, M. R. ;
Letzig, D. ;
Bormann, R. .
ACTA MATERIALIA, 2008, 56 (12) :2791-2798
[30]   The role of solute in grain refinement of magnesium [J].
Lee, YC ;
Dahle, AK ;
StJohn, DH .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2000, 31 (11) :2895-2906