Products of reaction between Bis(citrate)hydroxogermanic acid and organic molecules. Molecular and crystal structure of (HNad)2[Ge(HCit)2] • 4H2O

被引：5
作者：
Seifullina, I. I. [1 ]
Ilyukhin, A. B. [2 ]
Martsinko, E. E. [1 ]
Sergienko, V. S. [2 ]
Chebanenko, E. A. [1 ]
机构：
[1] Mechnikov Natl Univ, UA-65025 Odessa, Ukraine
[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 60卷 / 01期
关键词：
Compendex;
D O I：
10.1134/S0036023615010143
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Onium bis(citrate)germanates (HNad)(2)[Ge(HCit)(2)] center dot 4H(2)O (I), (HIm)(2)[Ge(HCit)(2)] center dot 2H(2)O (II), and (HInd)(2)[Ge(HCit)(2)] center dot 2H(2)O (III) (where Nad is nicotinamide, Im is imidazole, and Ind is isoniazid) were synthesized by the reaction between bis(citrate)hydroxogermanic(IV) acid (H5O2)[Ge(OH)(H(2)Cit)(H(2.5)Cit)](2) center dot 2CH(3)COOH center dot 2H(2)O (H(4)Cit is citric acid) and organic bases. The complexes were characterized by elemental analysis, thermogravimetry, and IR spectroscopy. The X-ray diffraction analysis of complex I was performed. The structural units of a crystal of complex I were found to be centrosymmetric complex [Ge(HCit)(2)](2-) anions, HNad(+) cations, and crystallization water molecules.
引用
收藏
页码：33 / 37
页数：5
相关论文
共 12 条
[1]  
[Anonymous], 1997, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B - Applications in Coordination, Organometallic, and Bioinorganic Chemistry
[2]  
[Anonymous], 1973, ANAL CHEM GERMANIUM
[3]   The co-crystal of two GRAS substances: (citric acid)•(nicotinamide). Formation of four hydrogen bonding heterosynthons in one co-crystal [J].
Lemmerer, Andreas ;
Bernstein, Joel .
CRYSTENGCOMM, 2010, 12 (07) :2029-2033
[4]   Bis(citrato)germanates of Bivalent 3d Metals (Fe, Co, Ni, Cu, Zn): Crystal and Molecular Structure of [Fe(H2O)6][Ge(HCit)2] • 4H2O [J].
Martsinko, E. E. ;
Minacheva, L. Kh ;
Pesaroglo, A. G. ;
Seifullina, I. I. ;
Churakov, A. V. ;
Sergienko, V. S. .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2011, 56 (08) :1243-1249
[5]  
Martsinko E. E., 2013, KOORDINATS KHIM, V39, P515
[6]   The Coordination Polymer Triaquabarium-μ-bis(citrato)germanate Trihydrate: Synthesis, Properties, and Molecular and Crystal Structure of {[Ge(μ-HCit)2Ba(H2O)3] • 3H2O}n [J].
Pesaroglo, A. G. ;
Martsinko, E. E. ;
Minacheva, L. Kh. ;
Seifullina, I. I. ;
Sergienko, V. S. .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2010, 55 (09) :1366-1372
[7]   Bis(citrato) germanate complexes with organic cations:: Crystal structure of (HNic)2[Ge(HCit)2]•3H2O [J].
Seifullina, I. I. ;
Pesaroglo, A. G. ;
Minacheva, L. Kh. ;
Martsinko, E. E. ;
Sergienko, V. S. .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 51 (12) :1892-1899
[8]   Synthesis, properties, and crystal structure of diphenylguanidinium bis(citrato)germanate hydrate (HDphg)2[Ge(HCit)2] • 1.08H2O [J].
Seifullina, I. I. ;
Pesaroglo, A. G. ;
Minacheva, L. Kh. ;
Martsinko, E. E. ;
Sergienko, V. S. .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 52 (04) :494-499
[9]   Bis(citrato)hydroxogermanic(IV) acid dimer [H5O2][Ge(H2Cit)(H2.5Cit)(OH)]2 • 2CH3COOH • 2H2O: Synthesis, properties, and crystal and molecular structure [J].
Seifullina, I. I. ;
Minacheva, L. Kh ;
Chebanenko, E. A. ;
Martsinko, E. E. ;
Sergienko, V. S. ;
Churakov, A. V. .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2011, 56 (12) :1886-1893
[10]   Behavior of tri(n-butyl)ammonium bis[citrato(3-)-O1,O3,O6]silicate in aqueous solution:: Analysis of a sol-gel process by small-angle neutron scattering [J].
Seiler, O ;
Burschka, C ;
Schwahn, D ;
Tacke, R .
INORGANIC CHEMISTRY, 2005, 44 (07) :2318-2325
12