Relative conversion of lower alkanes in their simultaneous partial gas-phase oxidation

被引：13

作者：

Arutyunov, VS

Rudakov, VM

Savchenko, VI

Sheverdenkin, EV

机构：

[1] Russian Acad Sci, Semenov Inst Chem Phys, Moscow 119991, Russia

[2] Russian Acad Sci, Inst Prob Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia

来源：

THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING | 2005年 / 39卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

Oxidation; Methane; Hydrocarbon; Alkane; Ethane;

D O I：

10.1007/s11236-005-0106-4

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Experimental and theoretical studies are undertaken to analyze the relative conversions of methane and ethane in their simultaneous partial oxidation and also the conversions of C-1-C-4 hydrocarbons in the oxidation of more complex mixtures that model real natural and associated gases. It is shown that, under the conditions at which C-1-C-4 hydrocarbons are oxidized to oxygenates and at an initial oxygen concentration of 4-16%, the rapid burnout of higher hydrocarbons is accompanied by an increase in the concentration of methane produced by their oxidative reforming.

引用

页码：487 / 492

页数：6