Surface-Enhanced Raman Scattering of Ag-Au Nanodisk Heterodimers

被引:32
作者
Liusman, Cipto [1 ]
Li, Hai [1 ]
Lu, Gang [1 ]
Wu, Jumiati [1 ]
Boey, Freddy [1 ]
Li, Shuzhou [1 ]
Zhang, Hua [1 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
基金
新加坡国家研究基金会;
关键词
PLASMONIC NANOSTRUCTURES; SILVER NANOPARTICLES; METAL NANOCRYSTALS; OPTICAL-PROPERTIES; SINGLE-MOLECULE; SHAPE; SPECTROSCOPY; RESONANCE; DIMER; GOLD;
D O I
10.1021/jp301739a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the fabrication of Ag-Au nanodisk heterodimers based on the modified on-wire lithography method and study their surface-enhanced Raman scattering (SEAS) properties experimentally and theoretically. The effects of disk thickness and gap size on SERS are explored. The SEAS properties of the optimized heterodimers are compared with those of the respective homodimers and single nanodisks excited at 633 and 488 nm. We found that the enhancement factor (EF) of Ag-Au heterodimers is greater at 633 nm than that at 488 nm, while their EF is between those of the Ag-Ag and Au-Au homodimers. At 488 nm excitation, the calculation indicates that the plasmon energy can be transferred from the Ag disk to the Au disk.
引用
收藏
页码:10390 / 10395
页数:6
相关论文
共 41 条
[1]   The use of nanocrystals in biological detection [J].
Alivisatos, P .
NATURE BIOTECHNOLOGY, 2004, 22 (01) :47-52
[2]  
Atwater HA, 2010, NAT MATER, V9, P205, DOI [10.1038/nmat2629, 10.1038/NMAT2629]
[3]   Fano Profiles Induced by Near-Field Coupling in Heterogeneous Dimers of Gold and Silver Nanoparticles [J].
Bachelier, G. ;
Russier-Antoine, I. ;
Benichou, E. ;
Jonin, C. ;
Del Fatti, N. ;
Vallee, F. ;
Brevet, P. -F. .
PHYSICAL REVIEW LETTERS, 2008, 101 (19)
[4]   Rationally designed nanostructures for surface-enhanced Raman spectroscopy [J].
Banholzer, Matthew J. ;
Millstone, Jill E. ;
Qin, Lidong ;
Mirkin, Chad A. .
CHEMICAL SOCIETY REVIEWS, 2008, 37 (05) :885-897
[5]   Silver-Based Nanodisk Codes [J].
Banholzer, Matthew J. ;
Osberg, Kyle D. ;
Li, Shuzhou ;
Mangelson, Bryan F. ;
Schatz, George C. ;
Mirkin, Chad A. .
ACS NANO, 2010, 4 (09) :5446-5452
[6]   Surface-enhanced Raman scattering [J].
Campion, A ;
Kambhampati, P .
CHEMICAL SOCIETY REVIEWS, 1998, 27 (04) :241-250
[7]   Chemical Fabrication of Heterometallic Nanogaps for Molecular Transport Junctions [J].
Chen, Xiaodong ;
Yeganeh, Sina ;
Qin, Lidong ;
Li, Shuzhou ;
Xue, Can ;
Braunschweig, Adam B. ;
Schatz, George C. ;
Ratner, Mark A. ;
Mirkin, Chad A. .
NANO LETTERS, 2009, 9 (12) :3974-3979
[8]   Plasmonic Control of the Shape of the Raman Spectrum of a Single Molecule in a Silver Nanoparticle Dimer [J].
Dadosh, T. ;
Sperling, J. ;
Bryant, G. W. ;
Breslow, R. ;
Shegai, T. ;
Dyshel, M. ;
Haran, G. ;
Bar-Joseph, I. .
ACS NANO, 2009, 3 (07) :1988-1994
[9]   Near Field Enhancement in Ag Au Nanospheres Heterodimers [J].
Encina, Ezequiel R. ;
Coronado, Eduardo A. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (32) :15908-15914
[10]   On the Far Field Optical Properties of Ag-Au Nanosphere Pairs [J].
Encina, Ezequiel R. ;
Coronado, Eduardo A. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (39) :16278-16284