Pressure-induced structural and electronic transitions of thiospinel Fe3S4

被引：4

作者：

Susilo, Resta A. ^{[1
]}

Li, Guowei ^{[2
]}

Feng, Jiajia ^{[1
]}

Deng, Wen ^{[1
]}

Yuan, Mingzhi ^{[1
]}

Li, Shujia ^{[1
]}

Dong, Hongliang ^{[1
]}

Chen, Bin ^{[1
]}

机构：

[1] Ctr High Pressure Sci & Technol Adv Res, Shanghai 201203, Peoples R China

[2] Max Planck Inst Chem Phys Solids, D-01187 Dresden, Germany

来源：

JOURNAL OF PHYSICS-CONDENSED MATTER | 2019年 / 31卷 / 09期

关键词：

thiospinel; phase transition; high pressure; X-RAY-DIFFRACTION; TERNARY CHROMIUM SULFIDES; MAGNETIC-PROPERTIES; GREIGITE; SPINEL; FE3O4; IRON; CONDUCTION; TRANSPORT;

D O I：

10.1088/1361-648X/aafadb

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

We report the investigations on the structural and electronic properties of an inverse spinel Fe3S4 at high pressures using synchrotron x-ray diffraction (XRD) and electrical transport measurements. Our XRD measurements at high pressures reveal an irreversible structural phase transformation on compression above similar to 3 GPa from a cubic spinel (Fd-3m space group) into a monoclinic Cr3S4-type structure (I2/m space group). Electrical transport measurements suggest that the high pressure monoclinic phase has a semiconducting behavior. This semiconducting behavior is found to persist up to the highest pressure of measurement of similar to 23 GPa. These results show that while Fe3S4 possesses similar high pressure structural properties with other thiospinels, the electronic properties under pressure show a rather strong similarity to its oxide counterpart, Fe3O4, at high pressures.

引用

页数：8

共 54 条

[1] Intricate relationship between pressure-induced electronic and structural transformations in FeCr2S4 [J].

Amiel, Y. ;

Rozenberg, G. Kh. ;

Nissim, N. ;

Milner, A. ;

Pasternak, M. P. ;

Hanfland, M. ;

Taylor, R. D. .

PHYSICAL REVIEW B, 2011, 84 (22)

[2] Widespread occurrence of greigite in the sediments of Lake Pannon:: Implications for environment and magnetostratigraphy [J].

Babinszki, Edit ;

Marton, Emo ;

Marton, Peter ;

Kiss, Laszlo Ferenc .

PALAEOGEOGRAPHY PALAEOCLIMATOLOGY PALAEOECOLOGY, 2007, 252 (3-4) :626-636

[3] FINITE ELASTIC STRAIN OF CUBIC CRYSTALS [J].

BIRCH, F .

PHYSICAL REVIEW, 1947, 71 (11) :809-824

[4] 3D Fe3S4 flower-like microspheres: high-yield synthesis via a biomolecule-assisted solution approach, their electrical, magnetic and electrochemical hydrogen storage properties [J].

Cao, Feng ;

Hu, Wen ;

Zhou, Liang ;

Shi, Weidong ;

Song, Shuyan ;

Lei, Yongqian ;

Wang, Song ;

Zhang, Hongjie .

DALTON TRANSACTIONS, 2009, (42) :9246-9252

[5] Magnetic structure of greigite (Fe3S4) probed by neutron powder diffraction and polarized neutron diffraction [J].

Chang, Liao ;

Rainford, Brian D. ;

Stewart, J. Ross ;

Ritter, Clemens ;

Roberts, Andrew P. ;

Tang, Yan ;

Chen, Qianwang .

JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH, 2009, 114

[6] Low-temperature magnetic properties of greigite (Fe3S4) [J].

Chang, Liao ;

Roberts, Andrew P. ;

Rowan, Christopher J. ;

Tang, Yan ;

Pruner, Petr ;

Chen, Qianwang ;

Horng, Chorng-Shern .

GEOCHEMISTRY GEOPHYSICS GEOSYSTEMS, 2009, 10

[7] Fundamental magnetic parameters from pure synthetic greigite (Fe3S4) [J].

Chang, Liao ;

Roberts, Andrew P. ;

Tang, Yan ;

Rainford, Brian D. ;

Muxworthy, Adrian R. ;

Chen, Qianwang .

JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH, 2008, 113 (B6)

[8] MAGNETIC STRUCTURE OF SPINEL FE3S4 [J].

COEY, JMD ;

SPENDER, MR ;

MORRISH, AH .

SOLID STATE COMMUNICATIONS, 1970, 8 (20) :1605-&

[9] A combined time-of-flight powder neutron and powder X-ray diffraction study of ternary chromium sulfides, VxCr3-xS4 (0<=x<=1.0) [J].

Colgan, DC ;

Powell, AV .

JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (09) :1579-1584

[10] Pressure dependence of the electrical transport in granular materials [J].

Creyssels, M. ;

Laroche, C. ;

Falcon, E. ;

Castaing, B. .

EUROPEAN PHYSICAL JOURNAL E, 2017, 40 (05) :1-20

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