Zinc(II) Coordination Polymers Based on Aromatic Tetracarboxylate: Syntheses, Structures, and Properties

被引：1
作者：
Li Xin [1 ]
Zhou Shang-Yong [1 ]
Tian Li [1 ]
机构：
[1] Tianjin Normal Univ, Tianjin Key Lab Struct & Performance Funct Mol, Key Lab Inorgan Organ Hybrid Funct Mat Chem, Minist Educ,Coll Chem, Tianjin 300387, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 31卷 / 02期
基金：
中国国家自然科学基金;
关键词：
bis(1,2,4-triazol-1-yl)ethane; biphenyl-3,3,5,5-tetracarboxylic acid; 3-D framework; supramolecular structure; METAL-ORGANIC FRAMEWORKS; HIGH H-2 ADSORPTION; FUNCTIONALIZATION; POLYCARBOXYLATE; HYDROGEN;
D O I：
10.11862/CJIC.2015.057
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two coordination compounds, namely ([Zn-2(bptc)(DMF)(2)(H2O)]center dot DMF center dot H2O}(n) (1) and ([Zn(bte)(bptc)(0.5)]DMF center dot 0.5H(2)O}(n) (2) (bte=bis (1,2,4-triazol-l-ybethane, H(4)bptc=bipheny1-3,3',5,5'-tetracarboxylic acid), have been synthesized and structurally characterized. 1 features a 3D framework with PtS-type topology, in which each binuclear second-building-unit (SBU){Zn-2(O2CR)(4)} is linked to four biphenyl connectors (and vice versa). 2 is 2D layers, which are interconnected by weak C-H center dot center dot center dot O interactions to lead to 3D supramolecular framework. The thermal stability, and fluorescent emission of the two complexes have also been discussed. CCDC:1018691, 1; 1018790, 2.
引用
收藏
页码：338 / 344
页数：7
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