First Molecules, Biological Chirality, Origin(s) of Life

被引：23

作者：

Caglioti, Luciano ^{[1
]}

Micskei, Karoly ^{[2
]}

Palyi, Gyula ^{[3
]}

机构：

[1] Univ Roma La Sapienza, Dept Chem & Technol Biologically Act Cpds, I-00185 Rome, Italy

[2] Univ Debrecen, Inst Chem, Debrecen, Hungary

[3] Univ Modena & Reggio Emilia, Dept Chem, Modena, Italy

来源：

CHIRALITY | 2011年 / 23卷 / 01期

关键词：

biological chirality; origin of; prebiotic enantioselection; life; enantioselection; by small molecules; soai reaction; asymmetric autocatalysis; single molecule; chirality of; ABSOLUTE ASYMMETRIC-SYNTHESIS; AUTOCATALYSIS; AMPLIFICATION; CHEMISTRY; CONJUNCTION;

D O I：

10.1002/chir.20796

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

Origin(s) of biological chirality appear(s) to be intimately connected to origin(s) of life. Prebiotic evolution toward these important turning points can be traced back to single chiral molecules. These can be small (monomeric) units as amino acids or monosaccharides or oligomers as oligo-RNA type molecules. Earlier speculations about these two kinds of entries to biological chirality are critically reviewed. Chirality 23: 65-68, 2011. (C) 2010 Wiley-Liss, Inc.

引用

页码：65 / 68

页数：4

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