A dinuclear pyrazolato-N:N′-bridged dinickel(II) complex of 1,3-bis(5-chlorosalicylideneamino)propan-2-ol

被引：6

作者：

Elerman, Y ^{[1
]}

Kara, H

Prout, K

Chippindale, A

机构：

[1] Ankara Univ, Fac Sci, Dept Engn Phys, TR-06100 Ankara, Turkey

[2] Univ Balikesir, Fac Arts & Sci, Dept Phys, TR-10100 Ankara, Turkey

[3] Univ Oxford, Chem Crystallog Lab, Oxford OX1 3PD, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2001年 / 57卷 / 02期

关键词：

D O I：

10.1107/S0108270100015808

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, mu-[1,3-bis(5-chloro-2-oxidobenzylideneamino)propan-2-olato(3-)]-O,N,O':O',N',O"-mu-(3,5-dimethylpyrazolato)-N:N' -dinickel(II), [Ni-2(C17H13Cl2N2O3)(C5H7N2)], has crystallographic mirror symmetry. The Ni atoms in the dinuclear structure are linked symmetrically by the N atoms of the 3,5-dimethylpyrazole group and by the alkoxo O atom. Each Ni-II ion is coordinated by two N atoms and two O atoms, forming a square plane with trans-N2O2 geometry.

引用

页码：149 / 150

页数：2

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