A dinuclear pyrazolato-N:N′-bridged dinickel(II) complex of 1,3-bis(5-chlorosalicylideneamino)propan-2-ol

被引:6
|
作者
Elerman, Y [1 ]
Kara, H
Prout, K
Chippindale, A
机构
[1] Ankara Univ, Fac Sci, Dept Engn Phys, TR-06100 Ankara, Turkey
[2] Univ Balikesir, Fac Arts & Sci, Dept Phys, TR-10100 Ankara, Turkey
[3] Univ Oxford, Chem Crystallog Lab, Oxford OX1 3PD, England
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2001年 / 57卷 / 02期
关键词
D O I
10.1107/S0108270100015808
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, mu-[1,3-bis(5-chloro-2-oxidobenzylideneamino)propan-2-olato(3-)]-O,N,O':O',N',O"-mu-(3,5-dimethylpyrazolato)-N:N' -dinickel(II), [Ni-2(C17H13Cl2N2O3)(C5H7N2)], has crystallographic mirror symmetry. The Ni atoms in the dinuclear structure are linked symmetrically by the N atoms of the 3,5-dimethylpyrazole group and by the alkoxo O atom. Each Ni-II ion is coordinated by two N atoms and two O atoms, forming a square plane with trans-N2O2 geometry.
引用
收藏
页码:149 / 150
页数:2
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