共 32 条
- [31] Verspui G, 2000, ANGEW CHEM INT EDIT, V39, P804, DOI 10.1002/(SICI)1521-3773(20000218)39:4<804::AID-ANIE804>3.0.CO
- [32] 2-Q
New catalysts for the alternating copolymerization of 4-tert-butylstyrene/CO
被引：28
作者：
Bastero, A
Ruiz, A
Reina, JA
Claver, C
Guerrero, AM
Jalón, FA
Manzano, BR
机构：
[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43005, Spain
[2] Univ Rovira & Virgili, Dept Quim Analit & Organ, Tarragona 43005, Spain
[3] Univ Castilla La Mancha, Dept Quim Inorgan Organ & Bioquim, Fac Quim, E-13071 Ciudad Real, Spain
关键词：
catalysis;
copolymerization;
styrene;
carbon monoxide;
palladium complexes;
nitrogen ligands;
D O I：
10.1016/S0022-328X(00)00670-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ;
081704 ;
摘要：
New cationic palladium(II) complexes, containing C-S-nitrogen chelate ligands with pyrazol moieties, catalyze the copolymerization of styrene with CO under mild conditions, to produce a syndiotactic copolymer. Molecular weight and polydispersity for the obtained polymers are among the best reported for bisnitrogen planar ligands. (C) 2001 Elsevier Science B.V. All rights reserved.
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页码：287 / 292
页数：6
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