A novel double-helical-chain coordination polymer constructed from 2,2′-biphenyldicarboxylate-linked binuclear-copper motif

被引：66

作者：

Lu, JY ^{[1
]}

Schauss, V ^{[1
]}

机构：

[1] Univ Houston Clear Lake, Dept Chem, Houston, TX 77058 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 10期

基金：

美国国家科学基金会;

关键词：

coordination polymer; one-dimensional structure; hydrothermal reaction; helical chain; binuclear copper; 2,2 '-biphenyldicarboxylate;

D O I：

10.1016/j.inoche.2003.06.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first I-D double-helical-chain coordination polymer, [(H(2)O)Cu(BPDC)] (2,2'-biphenyldicarboxylate), based upon the binuclear square pyramidal copper(II)-pair motifs has been synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction technique. [(H(2)O)Cu(BPDC)] crystallized in orthorhombic crystal system, space group Cmca with unit cell dimensions a = 21.073(6) Angstrom, b = 7.118(2) Angstrom and c = 17.670(5) Angstrom, Z = 8. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：1332 / 1334

页数：3

共 18 条

[1] 2 INTERPENETRATING 3D NETWORKS WHICH GENERATE SPACIOUS SEALED-OFF COMPARTMENTS ENCLOSING OF THE ORDER OF 20 SOLVENT MOLECULES IN THE STRUCTURES OF ZN(CN)(NO3)(TPT)(2/3)CENTER-DOT-SOLV (TPT=2,4,6-TRI(4-PYRIDYL)-1,3,5-TRIAZINE, SOLV=SIMILAR-TO-3/4C(2)H(2)CL(4)CENTER-DOT-3/4CH(3)OH OR SIMILAR-TO-3/2CHCL(3)CENTER-DOT-1/3CH(3)OH) [J].

BATTEN, SR ;

HOSKINS, BF ;

ROBSON, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (19) :5385-5386

[2] [(C6H5)(4)P](1)(INFINITY)[CU3I4] - THE FIRST COMPOUND WITH A HELICAL CHAIN OF FACE-SHARING TETRAHEDRA AS A STRUCTURAL ELEMENT [J].

HARTL, H ;

MAHDJOURHASSANABADI, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (18) :1841-1842

[3] Synthesis and characterization of spin-delocalized carboxylate-bridged Cu(I)-Cu(II) mixed-valence complexes having only oxygen donor ligands [J].

LeCloux, DD ;

Davydov, R ;

Lippard, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (27) :6810-6811

[4]

Lehn J. M., 1995, SUPRAMOLECULAR CHEM

[5] An extremely stable open-framework metal-organic polymer with expandable structure and selective adsorption capability [J].

Lu, JY ;

Babb, AM .

CHEMICAL COMMUNICATIONS, 2002, (13) :1340-1341

[6]

Lu JY, 2002, EUR J INORG CHEM, P1945

[7] A simultaneous reduction, substitution, and self-assembly reaction under hydrothermal conditions afforded the first diiodopyridine copper(I) coordination polymer [J].

Lu, JY ;

Babb, AM .

INORGANIC CHEMISTRY, 2002, 41 (06) :1339-1341

[8] Self-assembly of two-dimensional coordination polymers with rigid and flexible building blocks [J].

Lu, JY ;

Babb, A .

INORGANICA CHIMICA ACTA, 2001, 318 (1-2) :186-190

[9] A new 3-D neutral framework coordination polymer constructed via square pyramidal binuclear Cu(II) and nicotinato ligand [J].

Lu, JY ;

Babb, AM .

INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (12) :716-718

[10] An unprecedented mixed-valent-copper mutual-face-insertion layered metal-organic polymer displaying graphite-like properties [J].

Lu, JY ;

Runnels, KA .

INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (11) :678-681

← 1 2 →