Towards Homoleptic Borylene Complexes: Incorporation of Two Borylene Ligands into a Mononuclear Iridium Species

被引：29

作者：

Bertsch, Stefanie ^{[1
]}

Braunschweig, Holger ^{[1
]}

Christ, Bastian ^{[1
]}

Forster, Melanie ^{[1
]}

Schwab, Katrin ^{[1
]}

Radacki, Krzysztof ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 49期

关键词：

bis(borylene) complexes; boron; borylene complexes; coordination modes; iridium; TRANSITION-METAL-COMPLEXES; CP-ASTERISK-GA; COORDINATION MODES; THERMAL CONDITIONS; BRIDGING LIGAND; ER E; CHEMISTRY; TUNGSTEN; BORON; BOND;

D O I：

10.1002/anie.201004103

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Place two B: The isolation of the first terminal, mononuclear bis(borylene) complex (see structure) represents a significant step towards the synthesis of homoleptic borylene complexes, and also provides deeper insight into the bonding characteristics of borylene complexes in general. A preliminary elucidation of the question of how two terminal BR ligands affect each other when bound to the same metal center is presented. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9517 / 9520

页数：4

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