Electronic and Optical Properties of 2D Transition Metal Carbides and Nitrides (MXenes)

被引:1100
作者
Hantanasirisakul, Kanit [1 ,2 ]
Gogotsi, Yury [1 ,2 ]
机构
[1] Drexel Univ, AJ Drexel Nanomat Inst, Philadelphia, PA 19104 USA
[2] Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
关键词
2D transition metal carbides; 2D transition metal nitrides; electronic properties; MXenes; optical properties; optoelectronics; 2-DIMENSIONAL TITANIUM CARBIDE; INTRINSIC HALF-METALLICITY; MOLYBDENUM CARBIDE; TI3C2TX MXENE; SURFACE FUNCTIONALIZATION; RAMAN-SCATTERING; THEORETICAL PREDICTION; CATION INTERCALATION; TRANSPORT-PROPERTIES; MAGNETIC-PROPERTIES;
D O I
10.1002/adma.201804779
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2D transition metal carbides, carbonitrides, and nitrides, known as MXenes, are a rapidly growing family of 2D materials with close to 30 members experimentally synthesized, and dozens more studied theoretically. They exhibit outstanding electronic, optical, mechanical, and thermal properties with versatile transition metal and surface chemistries. They have shown promise in many applications, such as energy storage, electromagnetic interference shielding, transparent electrodes, sensors, catalysis, photothermal therapy, etc. The high electronic conductivity and wide range of optical absorption properties of MXenes are the key to their success in the aforementioned applications. However, relatively little is currently known about their fundamental electronic and optical properties, limiting their use to their full potential. Here, MXenes' electronic and optical properties from both theoretical and experimental perspectives, as well as applications related to those properties, are discussed, providing a guide for researchers who are exploring those properties of MXenes.
引用
收藏
页数:30
相关论文
共 248 条
[91]   Two-dimensional molybdenum carbides: potential thermoelectric materials of the MXene family [J].
Khazaei, Mohammad ;
Arai, Masao ;
Sasaki, Taizo ;
Estili, Mehdi ;
Sakka, Yoshio .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (17) :7841-7849
[92]   Novel Electronic and Magnetic Properties of Two-Dimensional Transition Metal Carbides and Nitrides [J].
Khazaei, Mohammad ;
Arai, Masao ;
Sasaki, Taizo ;
Chung, Chan-Yeup ;
Venkataramanan, Natarajan S. ;
Estili, Mehdi ;
Sakka, Yoshio ;
Kawazoe, Yoshiyuki .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (17) :2185-2192
[93]   Thermoelectric Properties of Two-Dimensional Molybdenum-Based MXenes [J].
Kim, Hyunho ;
Anasori, Babak ;
Gogotsi, Yury ;
Alshareef, Husam N. .
CHEMISTRY OF MATERIALS, 2017, 29 (15) :6472-6479
[94]   Metallic Ti3C2TX MXene Gas Sensors with Ultrahigh Signal-to-Noise Ratio [J].
Kim, Seon Joon ;
Koh, Hyeong-Jun ;
Ren, Chang E. ;
Kwon, Ohmin ;
Maleski, Kathleen ;
Cho, Soo-Yeon ;
Anasori, Babak ;
Kim, Choong-Ki ;
Choi, Yang-Kyu ;
Kim, Jihan ;
Gogotsi, Yury ;
Jung, Hee-Tae .
ACS NANO, 2018, 12 (02) :986-993
[95]   Surface group modification and carrier transport properties of layered transition metal carbides (Ti2CTx, T: -OH, -F and -O) [J].
Lai, Shen ;
Jeon, Jaeho ;
Jang, Sung Kyu ;
Xu, Jiao ;
Choi, Young Jin ;
Park, Jin-Hong ;
Hwang, Euyheon ;
Lee, Sungjoo .
NANOSCALE, 2015, 7 (46) :19390-19396
[96]   Electronic and optical properties of 2D graphene-like compounds titanium carbides and nitrides: DFT calculations [J].
Lashgari, H. ;
Abolhassani, M. R. ;
Boochani, A. ;
Elahi, S. M. ;
Khodadadi, J. .
SOLID STATE COMMUNICATIONS, 2014, 195 :61-69
[97]   Room Temperature Gas Sensing of Two-Dimensional Titanium Carbide (MXene) [J].
Lee, Eunji ;
Mohammadi, Armin Vahid. ;
Prorok, Barton C. ;
Yoon, Young Soo ;
Beidaghi, Majid ;
Kim, Dong-Joo .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (42) :37184-37190
[98]   Achieving Type I, II, and III Heterojunctions Using Functionalized MXene [J].
Lee, Youngbin ;
Hwang, Yubin ;
Chung, Yong-Chae .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (13) :7163-7169
[99]   Tunable Indirect to Direct Band Gap Transition of Monolayer Sc2CO2 by the Strain Effect [J].
Lee, Youngbin ;
Cho, Sung Beom ;
Chung, Yong-Chae .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (16) :14724-14728
[100]   Predicting stable phase monolayer Mo2C (MXene), a superconductor with chemically-tunable critical temperature [J].
Lei, Jincheng ;
Kutana, Alex ;
Yakobson, Boris I. .
JOURNAL OF MATERIALS CHEMISTRY C, 2017, 5 (14) :3438-3444