Supramolecular architectures featuring the antenna effect in solid state DSSCs

被引：20

作者：

Charalambidis, Georgios ^{[1
]}

Karikis, Kostas ^{[1
]}

Georgilis, Evangelos ^{[2
]}

M'Sabah, Bilel Louahem ^{[3
]}

Pellegrin, Yann ^{[4
]}

Planchat, Aurelien ^{[4
]}

Lucas, Bruno ^{[3
]}

Mitraki, Anna ^{[2
]}

Boucle, Johann ^{[3
]}

Odobel, Fabrice ^{[4
]}

Coutsolelos, Athanassios G. ^{[1
]}

机构：

[1] Univ Crete, Dept Chem, Bioinorgan Chem Lab, Voutes Campus, Iraklion 70013, Crete, Greece

[2] Univ Crete, IESL, Dept Mat Sci & Technol, FORTH, Iraklion 70013, Crete, Greece

[3] Univ Limoges, CNRS, XLIM, UMR 7252, 123 Ave Albert Thomas, F-87000 Limoges, France

[4] Univ LUNAM, Univ Nantes, CNRS, UMR CNRS 6230,CEISAM, 2 Rue Houssiniere, F-44322 Nantes 3, France

来源：

SUSTAINABLE ENERGY & FUELS | 2017年 / 1卷 / 02期

关键词：

SENSITIZED SOLAR-CELLS; LIGHT-HARVESTING ANTENNAS; ENERGY-TRANSFER; DYE; EFFICIENCY; COMPLEXES;

D O I：

10.1039/c6se00051g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hybrid artificial antenna systems, with implementation of nature's basic concept of self-organization of chromophores, attract vast interest due to their potential application in solar cells. Herein, we report a new supramolecular system comprising two porphyrins, a free base and its zinc analogue, bearing diphenylalanine units. The first is grafted on the TiO2 surface and plays the role of an initiator in the self-assembly of the second, inducing the formation of multi-molecular self-assembled spherical nanostructures. The achieved assemblies display an antenna effect and are used as biomimetic chromophore systems for dye-sensitized solar cells (DSSCs). This self-assembled antenna system gives a proof of concept that multichromophoric supramolecular assemblies based on hydrogen bonds can be of practical use for photovoltaic applications.

引用

页码：387 / 395

页数：9

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