Development of high power lithium-ion batteries: Layer Li[Ni0.4Co0.2Mn0.4]O2 and spinel Li[Li0.1Al0.05Mn1.85]O4

被引:16
作者
Myung, Seung-Taek [1 ]
Lee, Ki-Soo [2 ]
Sun, Yang-Kook [2 ]
Yashiro, Hitoshi [1 ]
机构
[1] Iwate Univ, Dept Chem Engn, Morioka, Iwate 0208551, Japan
[2] Hanyang Univ, Dept Energy Engn, Seoul 133791, South Korea
关键词
Li[Ni0.4Co0.2Mn0.4]O-2; Li[Li0.1Al0.05Mn1.85]O-4; Positive electrode; Lithium; Battery; ELECTROCHEMICAL PROPERTIES; CATHODE MATERIALS; INSERTION MATERIAL; STABILITY; CR;
D O I
10.1016/j.jpowsour.2010.09.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Layer Li[Ni0.4Co0.2Mn0.4]O-2 and lithium excess spinel Li[Li0.1Al0.05Mn1.85]O-4 were compared as positive electrode materials for high power lithium-ion batteries. Physical properties were examined by Rietveld refinement of X-ray diffraction pattern and scanning electron microscopic studies. From continuous charge and discharge tests at higher currents and different temperature environments using 3Ah class lithium-ion batteries, it was found that both materials presented plausible battery performances such as rate capability, cyclability at 60 degrees C at elevated temperature, and low temperature properties as well. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:7039 / 7043
页数:5
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