Electrophoretic study of cationic cobalt(III) complexes with [N2O] and [N2O2] Schiff base ligands

被引：10
|
作者：
Nesterenko, P [1 ]
Levitin, I [1 ]
Chernoglazova, N [1 ]
Paskonova, E [1 ]
Penner, N [1 ]
Tsikalova, M [1 ]
机构：
[1] Russian Acad Sci, Inst Organoelement Cpds, Moscow 117813, Russia
来源：
INORGANICA CHIMICA ACTA | 1998年 / 280卷 / 1-2期
关键词：
electrophoresis; cobalt complexes; alkyl complexes; Schiff base complexes;
D O I：
10.1016/S0020-1693(98)00211-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The electrophoretic migration behavior of acid-sensitive cationic alkylcobalt(III) complexes with tridentate Schiff bases and amines as well as that of related 'inorganic cobalt(III) chelates with tridentate and tetradentate Schiff bases was studied. A correlation of the electrophoretic mobility of the organocobalt complexes in question with their structure was established. An attempt to optimize the analytical procedures for capillary electrophoretic separation of these rather labile complex cations is outlined. Their decomposition in solutions under ambient conditions was surveyed using this technique. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：295 / 301
页数：7
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