Rhodium complexes supported on nanoporous activated carbon for selective hydroformylation of olefins

被引：21

作者：

Ganga, Venkata Subba Rao ^{[1
,2
]}

Dabbawala, Aasif A. ^{[2
]}

Munusamy, K. ^{[1
,2
]}

Abdi, Sayed H. R. ^{[1
,2
]}

Kureshy, Rukhsana I. ^{[1
,2
]}

Khan, Noor-ul H. ^{[1
,2
]}

Bajaj, Hari C. ^{[1
,2
]}

机构：

[1] CSIR CSMCRI, Inorgan Mat & Catalysis Div, Bhavnagar 364002, Gujarat, India

[2] CSIR CSMCRI, Acad Sci & Innovat Res, GB Marg, Bhavnagar 364002, Gujarat, India

来源：

CATALYSIS COMMUNICATIONS | 2016年 / 84卷

关键词：

Bio-wastes; Microporous-mesoporous carbon; High surface area; Hydroformylation; Olefins; Rhodium; CATALYTIC HYDROFORMYLATION; 1-HEXENE; PHOSPHINE; NANOTUBES; RUTHENIUM; OXIDE; RH/C;

D O I：

10.1016/j.catcom.2016.05.021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Activated carbon with nanoporous structure, high surface area (2500 m(2)/g) and total pore volume (2.35 cm(3)/g) was prepared from Mango seed shell (Mangifera indica L.) via chemical activation method and used as support to impregnate active hydroformylation rhodium complexes HRhCO(PPh3)(3) and Rh(acac)(CO)(2). The prepared catalysts were characterized by XRD, SEM, TEM, NMR, IR, TGA, and N-2 adsorption/desorption techniques. The supported catalysts have shown excellent selectivity for aldehydes (similar to 99%) in the hydroformylation of olefins with good stability and recyclability up to 4 cycles. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：21 / 24

页数：4

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