Self-Assembly of 2D Lanthanide-Metal Coordination Polymers Based on 5-Nitroisophthalic Acid Linker: Synthesis, Structures, and Luminescence

被引：1
作者：
Wang, S. -L. [1 ]
Zhang, L. -Y. [1 ]
Huang, Q. [1 ,2 ]
机构：
[1] Guangxi Univ Nationalities, Coll Chem & Chem Engn, Nanning 530006, Peoples R China
[2] Guangxi Key Lab Chem & Engn Forest Prod, Nanning, Peoples R China
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2015年 / 609卷 / 01期
关键词：
5-Nitroisophthalic acid; supramolecular network; fluorescence; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; SUPRAMOLECULAR ISOMERISM; COMPLEXES; CHANNELS; LIGAND; IONS; ARCHITECTURES; CADMIUM(II); CHEMISTRY;
D O I：
10.1080/15421406.2014.954307
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three 2D novel lanthanide-based metallic coordination frameworks involving the 5-nitroisophthalic acid ligand were characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction, namely, [Er(NIPH)(2)(H2O)(2)](H2O)(2) (1), [Eu-4(NIPH)(6)(H2O)(8)](H2O)(5) (2), and [Eu-4(NIPH)(6)(H2O)(6)](H2O)(4) (3), synthesized under hydrothermal conditions, self-assemble through Ln(2)[NIPH](2) building blocks to give a 2D coordination layer structure. The adjacent layers stack to form a 3D supramolecular framework through weak interactions, such as hydrogen bonding, pi-pi interactions, and lone pair-pi interactions. However, in 1 and 2 formed 2D 4-connected (4,4) topological network. In addition, in this work the photoluminescent property of the compound 3 has been studied.
引用
收藏
页码：161 / 170
页数：10
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