Synthesis of Atromentin and Its O-Alkylated Natural Products

被引：11
|
作者：
Ye, Yue Qi [1 ,2 ]
Koshino, Hiroyuki [1 ]
Abe, Naoki [2 ]
Nakamura, Takemichi [1 ]
Hashizume, Daisuke [1 ]
Takahashi, Shunya [1 ]
机构：
[1] RIKEN, Wako, Saitama 3510198, Japan
[2] Tokyo Univ Agr, Fac Appl Biosci, Dept Nutr Sci, Setagaya Ku, Tokyo 1568502, Japan
来源：
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 2010年 / 74卷 / 11期
关键词：
terphenyl; atromentin; single-crystal X-ray analysis; Suzuki-Miyaura coupling; DERIVATIVES;
D O I：
10.1271/bbb.100451
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The structure of a long-known natural pigment, atromentin, was established by a total synthesis based on double Suzuki-Miyaura coupling and by a single-crystal X-ray analysis of the synthetic sample thereby obtained. A similar strategy including ceric ammonium nitrate (CAN) oxidation was applied to prepare 2-O-methoxyatromentin and thelephantin I.
引用
收藏
页码：2342 / 2344
页数：3
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