Solvation of inorganic complexes: transfer chemical potentials for mono- and bi-nuclear cobalt(III) complexes to methanol plus water mixtures

被引：7

作者：

Abdur-Rashid, K

Dasgupta, TP

Blundell, NJ

Burgess, J ^{[1
]}

Drasdo, DN

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

[2] Univ W Indies, Dept Chem, Kingston 7, Jamaica

来源：

TRANSITION METAL CHEMISTRY | 2005年 / 30卷 / 02期

关键词：

D O I：

10.1007/s11243-004-2812-x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solubilities in MeOH-H2O mixtures at 298.2 K are reported for a number of salts of mono- and bi-nuclear cobalt(III) complexes. From these solubilities and published single ion transfer chemical potentials, on the TPTB (Ph4P+ = BPh4-) assumption, transfer chemical potentials have been derived for these mono- and bi-nuclear cobalt( III) complexes. The results and trends are discussed in relation to those for other complexes and ions in these binary aqueous solvent mixtures.

引用

页码：176 / 184

页数：9

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[41]

JANARDHANAN S, 1984, REV INORG CHEM, V6, P101

[42] Gibbs energies of transfer of cations from water to mixed aqueous organic solvents [J].