Solvation of inorganic complexes: transfer chemical potentials for mono- and bi-nuclear cobalt(III) complexes to methanol plus water mixtures

被引：7
作者：
Abdur-Rashid, K
Dasgupta, TP
Blundell, NJ
Burgess, J [1 ]
Drasdo, DN
机构：
[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England
[2] Univ W Indies, Dept Chem, Kingston 7, Jamaica
来源：
TRANSITION METAL CHEMISTRY | 2005年 / 30卷 / 02期
关键词：
D O I：
10.1007/s11243-004-2812-x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Solubilities in MeOH-H2O mixtures at 298.2 K are reported for a number of salts of mono- and bi-nuclear cobalt(III) complexes. From these solubilities and published single ion transfer chemical potentials, on the TPTB (Ph4P+ = BPh4-) assumption, transfer chemical potentials have been derived for these mono- and bi-nuclear cobalt( III) complexes. The results and trends are discussed in relation to those for other complexes and ions in these binary aqueous solvent mixtures.
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页码：176 / 184
页数：9
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