Continuous methanol synthesis directly from methane and steam over Cu(II)-exchanged mordenite

被引：4

作者：

Lee, Sae Ha

Kang, Jong Kyu

Park, Eun Duck ^{[1
]}

机构：

[1] Ajou Univ, Dept Chem Engn, Suwon 16499, South Korea

来源：

KOREAN JOURNAL OF CHEMICAL ENGINEERING | 2018年 / 35卷 / 11期

基金：

新加坡国家研究基金会;

关键词：

Methane Activation; Methanol; Copper; Mordenite; Steam; NATURAL-GAS; OXIDATION; ZEOLITES;

D O I：

10.1007/s11814-018-0150-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of methanol directly from methane and steam was observed over Cu ion-exchanged mordenite. Furthermore, the continuous production of methanol was achieved by co-feeding methane and steam over Cumordenite. The methanol production rate was comparable to that reported in the stepwise process in which activation, methane reaction, and extraction of methanol were carried out separately.

引用

收藏

页码：2145 / 2149

页数：5

相关论文

共 13 条

[1] Natural gas to synthesis gas - Catalysts and catalytic processes [J].

Aasberg-Petersen, K. ;

Dybkjaer, I. ;

Ovesen, C. V. ;

Schjodt, N. C. ;

Sehested, J. ;

Thomsen, S. G. .

JOURNAL OF NATURAL GAS SCIENCE AND ENGINEERING, 2011, 3 (02) :423-459

[2] Methane to methanol over copper mordenite: yield improvement through multiple cycles and different synthesis techniques [J].

Bozbag, Selmi E. ;

Alayon, Evalyn Mae C. ;

Pechacek, Jan ;

Nachtegaal, Maarten ;

Ranocchiari, Marco ;

van Bokhoven, Jeroen A. .

CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (13) :5011-5022

[3] Homogeneous Functionalization of Methane [J].

Gunsalus, Niles Jensen ;

Koppaka, Anjaneyulu ;

Park, Sae Hume ;

Bischof, Steven M. ;

Hashiguchi, Brian G. ;

Periana, Roy A. .

CHEMICAL REVIEWS, 2017, 117 (13) :8521-8573

[4] Oxidative Methane Upgrading [J].

Hammond, Ceri ;

Conrad, Sabrina ;

Hermans, Ive .

CHEMSUSCHEM, 2012, 5 (09) :1668-1686

[5] Natural Gas From Shale Bursts Onto the Scene [J].

Kerr, Richard A. .

SCIENCE, 2010, 328 (5986) :1624-1626

[6] Distinct activation of Cu-MOR for direct oxidation of methane to methanol [J].

Kim, Younhwa ;

Kim, Tae Yong ;

Lee, Hyunjoo ;

Yi, Jongheop .

CHEMICAL COMMUNICATIONS, 2017, 53 (29) :4116-4119

[7] Catalytic Oxidation of Methane into Methanol over Copper-Exchanged Zeolites with Oxygen at Low Temperature [J].

Narsimhan, Karthik ;

Iyoki, Kenta ;

Dinh, Kimberly ;

Roman-Leshkov, Yuriy .

ACS CENTRAL SCIENCE, 2016, 2 (06) :424-429

[8] Comparative Study of Diverse Copper Zeolites for the Conversion of Methane into Methanol [J].

Park, Min Bum ;

Ahn, Sang Hyun ;

Mansouri, Ali ;

Ranocchiari, Marco ;

van Bokhoven, Jeroen A. .

CHEMCATCHEM, 2017, 9 (19) :3705-3713

[9] The Direct Catalytic Oxidation of Methane to Methanol-A Critical Assessment [J].

Ravi, Manoj ;

Ranocchiari, Marco ;

van Bokhoven, Jeroen A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (52) :16464-16483

[10] Direct Conversion of Methane to Value-Added Chemicals over Heterogeneous Catalysts: Challenges and Prospects [J].

Schwach, Pierre ;

Pan, Xiulian ;

Bao, Xinhe .

CHEMICAL REVIEWS, 2017, 117 (13) :8497-8520