Carbon-Based Metal-Free ORR Electrocatalysts for Fuel Cells: Past, Present, and Future

被引：822

作者：

Yang, Lijun ^{[1
,2
]}

Shui, Jianglan ^{[3
]}

Du, Lei ^{[4
]}

Shao, Yuyan ^{[4
]}

Liu, Jun ^{[4
]}

Dai, Liming ^{[5
]}

Hu, Zheng ^{[1
,2
]}

机构：

[1] Nanjing Univ, Key Lab Mesoscop Chem MOE, Sch Chem & Chem Engn, Nanjing 210023, Jiangsu, Peoples R China

[2] Nanjing Univ, Jiangsu Prov Lab Nanotechnol, Sch Chem & Chem Engn, Nanjing 210023, Jiangsu, Peoples R China

[3] Beihang Univ, Sch Mat Sci & Engn, Beijing 100083, Peoples R China

[4] Pacific Northwest Natl Lab, Richland, WA 99352 USA

[5] Case Western Reserve Univ, Dept Macromol Sci & Engn, 10900 Euclid Ave, Cleveland, OH 44106 USA

来源：

ADVANCED MATERIALS | 2019年 / 31卷 / 13期

关键词：

carbon-based metal-free electrocatalysts; fuel cells; multidoping; nitrogen doping; oxygen reduction reaction; OXYGEN REDUCTION REACTION; NITROGEN-DOPED CARBON; HIGHLY EFFICIENT ELECTROCATALYSTS; ALKALINE POLYMER ELECTROLYTE; SURFACE-ENRICHED NITROGEN; GRAPHENE-BASED CATALYSTS; REACTION ACTIVE-SITES; MESOPOROUS CARBON; HYDROGEN EVOLUTION; CATHODE CATALYST;

D O I：

10.1002/adma.201804799

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Replacing precious platinum with earth-abundant materials for the oxygen reduction reaction (ORR) in fuel cells has been the objective worldwide for several decades. In the last 10 years, the fastest-growing branch in this area has been carbon-based metal-free ORR electrocatalysts. Great progress has been made in promoting the performance and understanding the underlying fundamentals. Here, a comprehensive review of this field is presented by emphasizing the emerging issues including the predictive design and controllable construction of porous structures and doping configurations, mechanistic understanding from the model catalysts, integrated experimental and theoretical studies, and performance evaluation in full cells. Centering on these topics, the most up-to-date results are presented, along with remarks and perspectives for the future development of carbon-based metal-free ORR electrocatalysts.

引用

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