Hydrolysis of alkenyl esters and ethers catalyzed by metal complexes

被引：50

作者：

Aoyama, H ^{[1
]}

Tokunaga, M

Hiraiwa, S

Shirogane, Y

Obora, Y

Tsuji, Y

机构：

[1] Hokkaido Univ, Grad Sch Sci, Ctr Catalysis Res, Sapporo, Hokkaido 0010021, Japan

[2] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0010021, Japan

[3] JST, Sapporo, Hokkaido 0010021, Japan

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 04期

关键词：

D O I：

10.1021/ol036228j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various kinds of transition metals catalyzed the hydrolysis of alkenyl esters and ethers under buffer-free, high concentration conditions compared to usual biocatalysts. Hydrolytic kinetic resolution of cis-2-tert-butylcyclohexyl vinyl ether was achieved by chiral (salen)Co complexes with good selectivity (k(rel) = 10.0).

引用

页码：509 / 512

页数：4

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