(Z)-selective cross-dimerization of arylacetylenes with silylacetylenes catalyzed by vinylideneruthenium complexes

被引：106

作者：

Katayama, H ^{[1
]}

Yari, H ^{[1
]}

Tanaka, M ^{[1
]}

Ozawa, F ^{[1
]}

机构：

[1] Kyoto Univ, Int Res Ctr Elements Sci, Chem Res Inst, Uji, Kyoto, Japan

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 34期

关键词：

D O I：

10.1039/b504436g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The vinylideneruthenium (II) complexes bearing bulky and basic tertiary phosphine ligands, RuCl2(=C=CHPh)L-2 (L = PPr3i, PCy3), serves as a good catalyst precursor for (Z)-selective cross-dimerization between arylacetylenes and silylacetylenes in the presence of N-methylpyrrolidine.

引用

页码：4336 / 4338

页数：3

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