Amorphous NiWO4 nanoparticles boosting the alkaline hydrogen evolution performance of Ni3S2 electrocatalysts

被引：116

作者：

Huang, Senchuan ^{[1
]}

Meng, Yuying ^{[1
,2
]}

Cao, Yangfei ^{[1
]}

Yao, Fen ^{[1
]}

He, Zhujie ^{[1
]}

Wang, Xuxu ^{[1
]}

Pan, Hui ^{[3
]}

Wu, Mingmei ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem, MOE Key Lab Bioinorgan & Synthet Chem, Sch Marine Sci, Guangzhou 510275, Peoples R China

[2] Jinan Univ, Inst Adv Wear & Corros Resistant & Funct Mat, Guangzhou 510632, Peoples R China

[3] Univ Macau, Inst Appl Phys & Mat Engn, Macau, Peoples R China

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2020年 / 274卷

基金：

中国国家自然科学基金;

关键词：

Nickel sulfide; Nickel tungstate; Hydrothermal; Amorphous nanoparticles; Hydrogen evolution reaction; BIFUNCTIONAL ELECTROCATALYSTS; EFFICIENT; CATALYST; ARRAYS; NIS;

D O I：

10.1016/j.apcatb.2020.119120

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Heazlewoodite nickel sulfide (Ni3S2) has become attractive for electrocatalytic hydrogen evolution reaction (HER). However, strong sulfur-hydrogen bonds (S-H-ads) formed on the surface of Ni3S2 greatly hinder the H-ads desorption and reduce HER activity. Herein, amorphous NiWO4 nanoparticles-decorated Ni3S2 electrocatalysts (NiWO4/Ni3S2) have been constructed via a two-step hydrothermal method. The heterostructures exhibit much better HER performance than original Ni3S2 by delivering current densities of -10 and -100 mA cm(-2) at low overpotentials of 136 and 274 mV, while those for Ni3S2 are 234 and 424 mV, respectively. Moreover, they display ultra-long stability of 75 h. Theoretical calculation proves the improved activity of NiWO4/Ni3S2 heterostructures is attributed to highly active interfaces between amorphous NiWO4 nanoparticles and Ni3S2 electrocatalysts. The strong electronic interaction between NiWO4 and Ni3S2 decreases the local electron density of Ni and S atoms, facilitates water adsorption on Ni-sites and optimizes hydrogen atom adsorption/desorption on adjacent S-sites with weakened S-H-ads.

引用

页数：9

共 50 条

[41] Sustainable hydrogen production [J].

Turner, JA .

SCIENCE, 2004, 305 (5686) :972-974

[42] Non-Noble Metal-based Carbon Composites in Hydrogen Evolution Reaction: Fundamentals to Applications [J].

Wang, Jing ;

Xu, Fan ;

Jin, Haiyan ;

Chen, Yiqing ;

Wang, Yong .

ADVANCED MATERIALS, 2017, 29 (14)

[43] One-step synthesis of V2O5/Ni3S2 nanoflakes for high electrochemical performance [J].

Wang, Xiuhua ;

Shi, Bo ;

Wang, Xiuqin ;

Gao, Jie ;

Zhang, Chen ;

Yang, Zhenzhen ;

Xie, Huifang .

JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (45) :23543-23549

[44] Efficient electrocatalysis of overall water splitting by ultrasmall NixCo3-xS4 coupled Ni3S2 nanosheet arrays [J].

Wu, Yuanyuan ;

Liu, Yipu ;

Li, Guo-Dong ;

Zou, Xu ;

Lian, Xinran ;

Wang, Dejun ;

Sun, Lei ;

Asefa, Tewodros ;

Zou, Xiaoxin .

NANO ENERGY, 2017, 35 :161-170

[45] In-situ activation of self-supported 3D hierarchically porous Ni3S2 films grown on nanoporous copper as excellent pH-universal electrocatalysts for hydrogen evolution reaction [J].

Yang, C. ;

Gao, M. Y. ;

Zhang, Q. B. ;

Zeng, J. R. ;

Li, X. T. ;

Abbott, A. P. .

NANO ENERGY, 2017, 36 :85-94

[46] MoS2-Ni3S2 Heteronanorods as Efficient and Stable Bifunctional Electrocatalysts for Overall Water Splitting [J].

Yang, Yaqing ;

Zhang, Kai ;

Ling, Huanlei ;

Li, Xiang ;

Chan, Hang Cheong ;

Yang, Lichun ;

Gao, Qingsheng .

ACS CATALYSIS, 2017, 7 (04) :2357-2366

[47] Three-dimensional-networked Ni2P/Ni3S2 heteronanoflake arrays for highly enhanced electrochemical overall-water-splitting activity [J].

Zeng, Lingyou ;

Sun, Kaian ;

Wang, Xiaobo ;

Liu, Yunqi ;

Pan, Yuan ;

Liu, Zhi ;

Cao, Dongwei ;

Song, Yue ;

Liu, Sihui ;

Liu, Chenguang .

NANO ENERGY, 2018, 51 :26-36

[48] Interface engineering: The Ni(OH)2/MoS2 heterostructure for highly efficient alkaline hydrogen evolution [J].

Zhang, Bao ;

Liu, Jia ;

Wang, Jinsong ;

Ruan, Yunjun ;

Ji, Xiao ;

Xu, Kui ;

Chen, Chi ;

Wan, Houzhao ;

Miao, Ling ;

Jiang, Jianjun .

NANO ENERGY, 2017, 37 :74-80

[49] Interface Engineering of MoS2/Ni3S2 Heterostructures for Highly Enhanced Electrochemical Overall-Water-Splitting Activity [J].

Zhang, Jian ;

Wang, Tao ;

Pohl, Darius ;

Rellinghaus, Bernd ;

Dong, Renhao ;

Liu, Shaohua ;

Zhuang, Xiaodong ;

Feng, Xinliang .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (23) :6702-6707

[50] Co3O4/Ni(OH)2 composite mesoporous nanosheet networks as a promising electrode for supercapacitor applications [J].

Zhong, Jin-Hui ;

Wang, An-Liang ;

Li, Gao-Ren ;

Wang, Jian-Wei ;

Ou, Yan-Nan ;

Tong, Ye-Xiang .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (12) :5656-5665

← 1 2 3 4 5 →