Effect of carbon black concentration in carbon fiber paper on the performance of low-temperature proton exchange membrane fuel cells

被引:26
作者
Liu, Ching-Han [1 ]
Ko, Tse-Hao [1 ]
Liao, Yuan-Kai [1 ]
机构
[1] Feng Chia Univ, Dept Mat Sci & Engn, Taichung 40724, Taiwan
关键词
fuel cell; gas diffusion layer; carbon fiber paper; carbon fiber felt; hot pressing; carbonization;
D O I
10.1016/j.jpowsour.2007.11.103
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study uses fuel cell gas diffusion layers (GDLs) made from carbon fiber paper containing carbon black in proton exchange membrane fuel cells (PEMFCs) in order to determine the relationship between carbon black content and fuel cell performance. The connection between fuel cell performance and the carbon black content of the carbon fiber paper is discussed, and the effects of carbon black on the carbon fiber paper's thickness, density, and surface resistivity are investigated. When a carbon fiber paper GDL contains 10 wt% phenolic resin and 2% carbon black, and reaction area was 25 cm(2) and operating temperature 40 degrees C, tests show that a carbon electrode fuel cell could achieve 1026.4 mA cm(-2) and maximum power of 612.8 mW cm(-2) under a 0.5 V load. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:80 / 85
页数:6
相关论文
共 25 条
[1]   Effects of the carbon powder characteristics in the cathode gas diffusion layer on the performance of polymer electrolyte fuel cells [J].
Antolini, E ;
Passos, RR ;
Ticianelli, EA .
JOURNAL OF POWER SOURCES, 2002, 109 (02) :477-482
[2]   Novel gas diffusion layer with water management function for PEMFC [J].
Chen, J ;
Matsuura, T ;
Hori, M .
JOURNAL OF POWER SOURCES, 2004, 131 (1-2) :155-161
[3]   A preliminary study of room temperature direct ethyl formate fuel cells for consumer electronic applications [J].
Chen, KY ;
Tseung, ACC .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 451 (1-2) :1-4
[4]   MECHANISMS FOR LITHIUM INSERTION IN CARBONACEOUS MATERIALS [J].
DAHN, JR ;
ZHENG, T ;
LIU, YH ;
XUE, JS .
SCIENCE, 1995, 270 (5236) :590-593
[5]   REPORT OF THE ELECTROLYTIC INDUSTRIES FOR THE YEAR 1992 [J].
FRITTS, SD ;
GOPAL, R .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (11) :3337-3363
[6]  
Hoogers G., 2002, FUEL CELL TECHNOLOGY
[7]   Oxygen mass transfer in PEM fuel cell gas diffusion layers [J].
Jeng, KT ;
Lee, SF ;
Tsai, GF ;
Wang, CH .
JOURNAL OF POWER SOURCES, 2004, 138 (1-2) :41-50
[8]   Diffusion layer parameters influencing optimal fuel cell performance [J].
Jordan, LR ;
Shukla, AK ;
Behrsing, T ;
Avery, NR ;
Muddle, BC ;
Forsyth, M .
JOURNAL OF POWER SOURCES, 2000, 86 (1-2) :250-254
[9]  
Ko TH, 1998, J APPL POLYM SCI, V70, P2409, DOI 10.1002/(SICI)1097-4628(19981219)70:12<2409::AID-APP13>3.0.CO
[10]  
2-0